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      Performance Comparison of Different Constructed Wetlands Designs for the Removal of Personal Care Products

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          Abstract

          This research investigates the performance of four types of constructed wetlands (CWs): free water surface CW (FWSCW), horizontal flow CW (HFCW), vertical flow CW (VFCW), and hybrid CW (HCW) for the removal of 20 personal care products (PCPs), based on secondary data compiled for 137 CWs reported in 39 peer reviewed journal papers. In spite of considerable variation in the re-moval efficiency of PCPs, CWs prove to be a promising treatment technology. The average removal efficiency of 15 widely studied PCPs ranged from 9.0% to 84%. Although CWs effectively reduced the environmental risks caused by many PCPs, triclosan was still classified under high risk category based on effluent concentration. Five other PCPs were classified under medium risk category (triclocarban > methylparaben > galaxolide > oxybenzone > methyl dihydrojasmonate). In most of the examined PCPs, adsorption and/or sorption is the most common removal mechanism followed by biodegradation and plant uptake. The comparatively better performance of HCW followed by VFCW, HFCW, and FWSCW might be due to the co-existence of aerobic and anaerobic conditions, and longer hydraulic retention time enhancing the removal of PCPs (e.g., triclosan, methyl dihydro-jasmonate, galaxolide, tonalide, and oxybenzone), which are removed under both conditions and by adsorption/sorption processes.

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          Occurrence of pharmaceutical compounds in urban wastewater: removal, mass load and environmental risk after a secondary treatment--a review.

          This review focuses on 118 pharmaceuticals, belonging to seventeen different therapeutic classes, detected in raw urban wastewater and effluent from an activated sludge system, a usual treatment adopted for urban wastewaters worldwide prior to final discharge into surface water bodies. Data pertaining to 244 conventional activated sludge systems and 20 membrane biological reactors are analysed and the observed ranges of variability of each selected compound in their influent and effluent reported, with particular reference to the substances detected most frequently and in higher concentrations. A snapshot of the ability of these systems to remove such compounds is provided by comparing their global removal efficiencies for each substance. Where possible, the study then evaluates the average daily mass load of the majority of detected pharmaceuticals exiting the secondary treatment step. The final part of the review provides an assessment of the environmental risk posed by their presence in the secondary effluent by means of the risk quotient that is the ratio between the average pharmaceutical concentration measured in the secondary effluent and the predicted no-effect concentration. Finally, mass load rankings of the compounds under review are compared with those based on their risk level. This analysis shows that the highest amounts discharged through secondary effluent pertain to one antihypertensive, and several beta-blockers and analgesics/anti-inflammatories, while the highest risk is posed by antibiotics and several psychiatric drugs and analgesics/anti-inflammatories. These results are reported with a view to aiding scientists and administrators in planning measures aiming to reduce the impact of treated urban wastewater discharge into surface water bodies. Copyright © 2012 Elsevier B.V. All rights reserved.
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            Occurrence and fate of emerging contaminants in municipal wastewater treatment plants from different geographical regions-a review.

            Emerging contaminants, such as antibiotics, pharmaceuticals, personal care products, hormones, and artificial sweeteners, are recognized as new classes of water contaminants due to their proven or potential adverse effects on aquatic ecosystems and human health. This review provides comprehensive data on the occurrence of 60 emerging contaminants (ECs) in influent, treated effluent, sludge, and biosolids in wastewater treatment plants (WWTPs). In particular, data on the occurrence of ECs in the influents and effluents of WWTPs are systematically summarized and categorized according to geographical regions (Asia, Europe, and North America). The occurrence patterns of ECs in raw influent and treated effluents of WWTPs between geographical regions were compared and evaluated. Concentrations of most ECs in raw influent in Asian region tend to be higher than those in European and North American countries. Many antibiotics were detected in the influents and effluents of WWTPs at concentrations close to or exceeding the predicted no-effect concentrations (PNECs) for resistance selection. The efficacy of EC removal by sorption and biodegradation during wastewater treatment processes are discussed in light of kinetics and parameters, such as sorption coefficients (Kd) and biodegradation constants (kbiol), and physicochemical properties (i.e. log Kowand pKa). Commonly used sampling and monitoring strategies are critically reviewed. Analytical research needs are identified, and novel investigative approaches for future monitoring studies are proposed.
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              Environmental risk assessment of pharmaceutical residues in wastewater effluents, surface waters and sediments.

              Pharmaceutical residues in the environment, and their potential toxic effects, have been recognized as one of the emerging research area in the environmental chemistry. The increasing attention, on pharmaceutical residues as potential pollutants, is due that they often have similar physico-chemical behaviour than other harmful xenobiotics which are persistent or produce adverse effects. In addition, by contrast with regulated pollutants, which often have longer environmental half-lives, its continuous introduction in the environment may make them "pseudopersistents". Pharmaceutical residues and/or their metabolites are usually detected in the environment at trace levels, but, even that, low concentration levels (ng/L or microg/L) can induce to toxic effects. In particular, this is the case of antibiotics and steroids that cause resistance in natural bacterial populations or endocrine disruption effects. In this study, an overview of the environmental occurrence and ecological risk assessment of pharmaceutical residues is presented from literature data. Risk Quotient method (RQ) was applied as a novel approach to estimate the environmental risk of pharmaceuticals that are most frequently detected in wastewater effluents, surface waters and sediments.
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                Author and article information

                Journal
                Int J Environ Res Public Health
                Int J Environ Res Public Health
                ijerph
                International Journal of Environmental Research and Public Health
                MDPI
                1661-7827
                1660-4601
                29 April 2020
                May 2020
                : 17
                : 9
                : 3091
                Affiliations
                [1 ]Institut de physique du globe de Paris, Université de Paris, CNRS, F-75005 Paris, France; vanhullebusch@ 123456ipgp.fr
                [2 ]Water Treatment and Management Consultancy, B.V., 2289 ED Rijswijk, The Netherlands
                Author notes
                Author information
                https://orcid.org/0000-0002-3539-0833
                https://orcid.org/0000-0002-1519-1925
                Article
                ijerph-17-03091
                10.3390/ijerph17093091
                7246432
                32365511
                41f6efcf-ff89-4541-94df-0b060bc65c0f
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 25 March 2020
                : 25 April 2020
                Categories
                Review

                Public health
                artificial aeration,constructed wetlands,personal care products,physicochemical properties,removal efficiency,removal mechanisms

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