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      Akaganeite nanorices deposited muscovite mica surfaces as sunlight active green photocatalyst

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          Abstract

          Thin films of akaganeite [FeO(OH)] nanorices deposited muscovite mica (ANPM) surfaces are synthesized using the facile urea assisted controlled self-assembly technique. The synthesized materials are characterized using scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy, atomic force microscopy, X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy and thermogravimetric analysis (TGA). The prepared nanorices on mica surfaces show average particle length and width of 200 and 50 nm, respectively. Synthesized material acts as an efficient photocatalyst under UV and sunlight conditions as demonstrated by the degradation of standard methylene blue (MB) solution. The MB degradation efficiencies of the catalyst under exposure to 180 min sunlight and UV are 89% and 87.5%, respectively, which shows that the catalyst is more highly active under sunlight than under UV light. Therefore, the synthesized material is a potential green photocatalyst in efficient treatment of industrial dye effluents under direct sunlight.

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          Most cited references43

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          Photocatalytic degradation pathway of methylene blue in water

          A Houas (2001)
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            Recent developments of zinc oxide based photocatalyst in water treatment technology: A review.

            Today, a major issue about water pollution is the residual dyes from different sources (e.g., textile industries, paper and pulp industries, dye and dye intermediates industries, pharmaceutical industries, tannery and craft bleaching industries, etc.), and a wide variety of persistent organic pollutants have been introduced into our natural water resources or wastewater treatment systems. In fact, it is highly toxic and hazardous to the living organism; thus, the removal of these organic contaminants prior to discharge into the environment is essential. Varieties of techniques have been employed to degrade those organic contaminants and advanced heterogeneous photocatalysis involving zinc oxide (ZnO) photocatalyst appears to be one of the most promising technology. In recent years, ZnO photocatalyst have attracted much attention due to their extraordinary characteristics. The high efficiency of ZnO photocatalyst in heterogeneous photocatalysis reaction requires a suitable architecture that minimizes electron loss during excitation state and maximizes photon absorption. In order to further improve the immigration of photo-induced charge carriers during excitation state, considerable effort has to be exerted to further improve the heterogeneous photocatalysis under UV/visible/solar illumination. Lately, interesting and unique features of metal doping or binary oxide photocatalyst system have gained much attention and became favourite research matter among various groups of scientists. It was noted that the properties of this metal doping or binary oxide photocatalyst system primarily depend on the nature of the preparation method and the role of optimum dopants content incorporated into the ZnO photocatalyst. Therefore, this paper presents a critical review of recent achievements in the modification of ZnO photocatalyst for organic contaminants degradation.
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              Use of iron oxide nanomaterials in wastewater treatment: a review.

              Nowadays there is a continuously increasing worldwide concern for the development of wastewater treatment technologies. The utilization of iron oxide nanomaterials has received much attention due to their unique properties, such as extremely small size, high surface-area-to-volume ratio, surface modifiability, excellent magnetic properties and great biocompatibility. A range of environmental clean-up technologies have been proposed in wastewater treatment which applied iron oxide nanomaterials as nanosorbents and photocatalysts. Moreover, iron oxide based immobilization technology for enhanced removal efficiency tends to be an innovative research point. This review outlined the latest applications of iron oxide nanomaterials in wastewater treatment, and gaps which limited their large-scale field applications. The outlook for potential applications and further challenges, as well as the likely fate of nanomaterials discharged to the environment were discussed. Copyright © 2012 Elsevier B.V. All rights reserved.
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                Author and article information

                Journal
                R Soc Open Sci
                R Soc Open Sci
                RSOS
                royopensci
                Royal Society Open Science
                The Royal Society
                2054-5703
                March 2019
                27 March 2019
                27 March 2019
                : 6
                : 3
                : 182212
                Affiliations
                [1 ]Academy of Sri Lanka Institute of Nanotechnology (SLINTEC Academy) , Mahenwatte, Pitipana, Homagama 10206, Sri Lanka
                [2 ]Sri Lanka Institute of Nanotechnology (SLINTEC) , Nanotechnology and Science Park, Mahenwatte, Pitipana, Homagama 10206, Sri Lanka
                [3 ]Postgraduate Institute of Science (PGIS), University of Peradeniya , Peradeniya 20400, Sri Lanka
                [4 ]Department of Science and Technology, Uva Wellassa University , Passara Road, Badulla 90000, Sri Lanka
                [5 ]Department of Chemistry, Faculty of Science, University of Peradeniya , Peradeniya 20400, Sri Lanka
                [6 ]Department of Geology, Faculty of Science, University of Peradeniya , Peradeniya 20400, Sri Lanka
                [7 ]Department of Chemistry, Faculty of Science, University of Colombo , Colombo 00300, Sri Lanka
                Author notes
                Author for correspondence: K. M. Nalin de Silva e-mail: nalinds@ 123456slintec.lk

                This article has been edited by the Royal Society of Chemistry, including the commissioning, peer review process and editorial aspects up to the point of acceptance.

                Electronic supplementary material is available online at https://dx.doi.org/10.6084/m9.figshare.c.4440176.

                Author information
                http://orcid.org/0000-0001-9832-6807
                http://orcid.org/0000-0003-3943-5362
                http://orcid.org/0000-0001-7483-5922
                http://orcid.org/0000-0003-3219-3233
                Article
                rsos182212
                10.1098/rsos.182212
                6458388
                435d4db2-db07-47ef-8e12-b8fa2681df53
                © 2019 The Authors.

                Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.

                History
                : 22 January 2019
                : 25 February 2019
                Funding
                Funded by: National Research Council Sri Lanka, http://dx.doi.org/10.13039/100008968;
                Award ID: 16-123
                Categories
                1002
                78
                117
                131
                Chemistry
                Research Article
                Custom metadata
                March, 2019

                akaganeite nanorices,sunlight active,mica surfaces,green photocatalyst

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