Spectroscopic characterization of graphene films grown on Pt (111)
  surface by chemical vapor deposition of ethylene

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Abstract

This work reports the peculiar properties of a graphene film prepared by the chemical vapor deposition (CVD) of ethylene in high vacuum on a well oriented and carefully cleaned Pt(111) crystal surface maintained at high temperature. In-situ and ex-situ characterization techniques (low energy electron diffraction, high resolution electron energy loss spectroscopy, scanning electron microscopy and Raman micro-spectroscopy) used here indicate the prevalence of single layer regions and the presence of two different orientations of the graphene sheets with respect to the Pt(111) substrate. In most of the deposited area evidence is found of a compressive stress for the graphene lattice, as a net result of the growth process on a metal substrate. This graphene film grown on Pt(111) exhibits a lower degree of order and of homogeneity with respect to the exfoliated graphene on Si/SiO2, as it is found generally for graphene on metals, but several characterization techniques indicates a better quality than in previous deposition experiments on the same metal substrate.

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Compression Behavior of Single-layer Graphene

Rashid Jalil, Konstantinos Papagelis, Georgia Tsoukleri … (2010)

Central to most applications involving monolayer graphene is its mechanical response under various stress states. To date most of the work reported is of theoretical nature and refers to tension and compression loading of model graphene. Most of the experimental work is indeed limited to bending of single flakes in air and the stretching of flakes up to typically ~1% using plastic substrates. Recently we have shown that by employing a cantilever beam we can subject single graphene into various degrees of axial compression. Here we extend this work much further by measuring in detail both stress uptake and compression buckling strain in single flakes of different geometries. In all cases the mechanical response is monitored by simultaneous Raman measurements through the shift of either the G or 2D phonons of graphene. In spite of the infinitely small thickness of the monolayers, the results show that graphene embedded in plastic beams exhibit remarkable compression buckling strains. For large length (l)-to-width (w) ratios (> 0.2) the buckling strain is of the order of -0.5% to -0.6%. However, for l/w <0.2 no failure is observed for strains even higher than -1%. Calculations based on classical Euler analysis show that the buckling strain enhancement provided by the polymer lateral support is more than six orders of magnitude compared to suspended graphene in air.

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Growth and atomic-scale characterizations of graphene on multifaceted textured Pt foils prepared by chemical vapor deposition.

M. Liu, S. Xie, Y. Gao … (2011)

The synthesis of centimeter-scale uniform graphene on Pt foils was accomplished via a traditional ambient pressure chemical vapor deposition (CVD) method. Using scanning electron microscopy (SEM) and Raman spectroscopy, we reveal the macroscopic continuity, the thickness, as well as the defect state of as-grown graphene. Of particular importance is that the Pt foils after CVD growth have multifaceted texture, which allows us to explore the substrate crystallography effect on the growth rate and the continuity of graphene. By virtue of atomically resolved scanning tunneling microscopy (STM), we conclude that graphene grows mainly in registry with the symmetries of Pt(111), Pt(110), and Pt(100) facets, leading to hexagonal lattices and striped superstructures. Nevertheless, the carbon lattices on interweaving facets with different identities are connected seamlessly, which ensure the graphene growth from nanometer to micrometer levels. With these results, another prototype for clarifying the preliminary growth mechanism of the CVD process is demonstrated as an analogue of graphene on Cu foils. © 2011 American Chemical Society