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      Phenol Removal from Aqueous Environment by Adsorption onto Pomegranate Peel Carbon

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          Abstract

          Introduction

          Phenol and its derivatives are the most common poisonous compounds which are stable in aqueous media and lead to many health issues. In this study, application of the carbon resulted from pomegranate peel is investigated in removal of phenol by adsorption method.

          Methods

          to perform this cross-sectional study, first, samples of phenol with concentrations of 10 to 100 mg/L were prepared for six months in 2016. Then, the impacts of parameters such as pH, adsorbent dosage, contact time, and initial concentration of phenol in adsorption process were investigated independently in Gonabad Chemistry Lab using a spectrophotometer at 505 nm as the wavelength. Furthermore, adherence of the samples to the isotherm models of Langmuir and Freundlich was determined by Excel 2016 and descriptive statistical methods were then reported.

          Results

          The obtained results demonstrated a maximum adsorption capacity (ash) of 148.38 mgg-1 at pH 7, initial concentration of 100 mg L −1, and temperature of 23 ± 2 °C. The phenol removal rate was found to correlate directly to the adsorbent dosage and contact time, and inversely to the initial concentration of phenol. In addition, the investigations showed that the adsorption of phenol on the pomegranate peel ash follows the Freundlich model well with a correlation coefficient of R2 0.9056.

          Conclusion

          Pomegranate peel ash could be used as an efficient and low-cost adsorbent for phenol removal from aqueous media.

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          Most cited references51

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          Technologies for the removal of phenol from fluid streams: a short review of recent developments.

          The available technologies for the abatement of phenol from water and gaseous streams are briefly reviewed, and the recent advancements summarized. Separation technologies such as distillation, liquid-liquid extraction with different solvents, adsorption over activated carbons and polymeric and inorganic adsorbents, membrane pervaporation and membrane-solvent extraction, have been discussed. Destruction technologies such as non-catalytic, supercritical and catalytic wet air oxidation, ozonation, non-catalytic, catalytic and enzymatic peroxide wet oxidation, electrochemical and photocatalytic oxidation, supercritical wet gasification, destruction with electron discharges as well as biochemical treatments have been considered. As for the abatement of phenol from gases, condensation, absorption in liquids, adsorption on solids, membrane separation, thermal, catalytic, photocatalytic and biological oxidation have also been considered. The experimental conditions and the performances of the different techniques have been compared.
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            Removal of phenol from aqueous solutions by adsorption onto activated carbon prepared from biomass material.

            Activated carbon derived from rattan sawdust (ACR) was evaluated for its ability to remove phenol from an aqueous solution in a batch process. Equilibrium studies were conducted in the range of 25-200mg/L initial phenol concentrations, 3-10 solution pH and at temperature of 30 degrees C. The experimental data were analyzed by the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherm models. Equilibrium data fitted well to the Langmuir model with a maximum adsorption capacity of 149.25mg/g. The dimensionless separation factor RL revealed the favorable nature of the isotherm of the phenol-activated carbon system. The pseudo-second-order kinetic model best described the adsorption process. The results proved that the prepared activated carbon was an effective adsorbent for removal of phenol from aqueous solution.
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              The Chemistry of Phenols

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                Author and article information

                Journal
                Electron Physician
                Electron Physician
                Electronic physician
                Electronic Physician
                Electronic physician
                2008-5842
                November 2016
                25 November 2016
                : 8
                : 11
                : 3248-3256
                Affiliations
                [1 ]Ph.D. of Environmental Health, Assistant Professor, Department of Environmental Health Engineering, School of Public Health, Social Development & Health Promotion Research Center, Gonabad University of Medical Sciences, Gonabad, Iran
                [2 ]M.Sc. of Environmental Health, Instructor, Department of Environmental Health Engineering, School of Public Health, Torbat Heydarieh University of Medical Sciences, Torbat Heydarieh, Iran
                [3 ]M.Sc. of Environmental Health, Senior Lecturer, Department of Environmental Health Engineering, School of Public Health, Mashhad University of Medical Science, Mashhad, Iran
                [4 ]M.Sc. of Environmental Health, Senior Lecturer, Department of Environmental Health Engineering, School of Public Health, Iranshar University of Medical Sciences, Iranshar, Iran
                [5 ]M.Sc. of Environmental Health, Senior Lecturer, Department of Environmental Health Engineering, School of Public Health, Social Development & Health Promotion Research Center, Gonabad University of Medical Science, Gonabad, Iran
                Author notes
                Corresponding author: Hamed Biglari, Department of Environmental Health Engineering, School of Public Health, Social Development & Health Promotion Research Center, Gonabad University of Medical Science, Gonabad, Iran., Tel: +98.5157225027, Fax: +98.5157223814, Email: Biglari.h@ 123456gmu.ac.ir
                Article
                epj-08-3248
                10.19082/3248
                5217818
                46da2544-8fbc-440f-a2ce-cc4ae96565cd
                © 2016 The Authors

                This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.

                History
                : 21 June 2016
                : 19 September 2016
                Categories
                Original Article

                adsorption,aqueous solution,pomegranate peel,activated carbon,freundlich,langmuir isotherm

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