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      Recent advances in the Heck–Matsuda reaction in heterocyclic chemistry

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      Tetrahedron
      Elsevier BV

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          Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis.

          Interest in catalysis by metal nanoparticles (NPs) is increasing dramatically, as reflected by the large number of publications in the last five years. This field, "semi-heterogeneous catalysis", is at the frontier between homogeneous and heterogeneous catalysis, and progress has been made in the efficiency and selectivity of reactions and recovery and recyclability of the catalytic materials. Usually NP catalysts are prepared from a metal salt, a reducing agent, and a stabilizer and are supported on an oxide, charcoal, or a zeolite. Besides the polymers and oxides that used to be employed as standard, innovative stabilizers, media, and supports have appeared, such as dendrimers, specific ligands, ionic liquids, surfactants, membranes, carbon nanotubes, and a variety of oxides. Ligand-free procedures have provided remarkable results with extremely low metal loading. The Review presents the recent developments and the use of NP catalysis in organic synthesis, for example, in hydrogenation and C--C coupling reactions, and the heterogeneous oxidation of CO on gold NPs.
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            The heck reaction as a sharpening stone of palladium catalysis.

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              Palladium-catalyzed vinylic hydrogen substitution reactions with aryl, benzyl, and styryl halides

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                Author and article information

                Journal
                Tetrahedron
                Tetrahedron
                Elsevier BV
                00404020
                April 2011
                April 2011
                : 67
                : 16
                : 2815-2831
                Article
                10.1016/j.tet.2011.02.051
                4944fad9-aaba-4935-9428-817c0ace61b6
                © 2011

                http://www.elsevier.com/tdm/userlicense/1.0/

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