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      Tin Dioxide Thin Film with UV-enhanced Acetone Detection in Microwave Frequency Range

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          Abstract

          In this paper, the UV illumination effect for microwave gas sensors based on the tin dioxide was verified. A UV LED with emission wavelength close to the absorption edge of the SnO 2 gas-sensing layer was selected as the UV source. The developed gas sensors were tested under exposure to acetone in the 0–200 ppm range at room temperature. The sensor’s complex reflection coefficient corresponding to target gas concentration was measured with the use of a five-port reflectometer system exhibiting enhanced uncertainty distribution, which allows for the detection of low gas concentration. The UV illumination significantly emphasizes the sensors’ response in terms of both magnitude and phase for low gas concentrations, in contrast to previously reported results, in which only the reflection coefficient’s phase was affected. The highest responses were obtained for modulated UV illumination.

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          Si:WO(3) Sensors for highly selective detection of acetone for easy diagnosis of diabetes by breath analysis.

          Acetone in the human breath is an important marker for noninvasive diagnosis of diabetes. Here, novel chemo-resistive detectors have been developed that allow rapid measurement of ultralow acetone concentrations (down to 20 ppb) with high signal-to-noise ratio in ideal (dry air) and realistic (up to 90% RH) conditions. The detector films consist of (highly sensitive) pure and Si-doped WO(3) nanoparticles (10-13 nm in diameter) made in the gas phase and directly deposited onto interdigitated electrodes. Their sensing properties (selectivity, limit of detection, response, and recovery times) have been investigated as a function of operating temperature (325-500 degrees C), relative humidity (RH), and interfering analyte (ethanol or water vapor) concentration. It was found that Si-doping increases and stabilizes the acetone-selective epsilon-WO(3) phase while increasing its thermal stability and, thus, results in superior sensing performance with an optimum at about 10 mol % Si content. Furthermore, increasing the operation temperature decreased the detector response to water vapor, and above 400 degrees C, it was ( or=1800 ppb) can be clearly distinguished by a remarkable gap (40%) in sensor response. As a result, these solid state detectors may offer a portable and cost-effective alternative to more bulky systems for noninvasive diabetes detection by human breath analysis.
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            Quantitative Analysis of Urine Vapor and Breath by Gas-Liquid Partition Chromatography

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              Determination of acetone in human breath by gas chromatography–mass spectrometry and solid-phase microextraction with on-fiber derivatization

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                Author and article information

                Journal
                Micromachines (Basel)
                Micromachines (Basel)
                micromachines
                Micromachines
                MDPI
                2072-666X
                30 August 2019
                September 2019
                : 10
                : 9
                : 574
                Affiliations
                Department of Electronics, AGH University of Science and Technology, 30059 Krakow, Poland
                Author notes
                [* ]Correspondence: artur.rydosz@ 123456agh.edu.pl ; Tel.: +48-126-172-594
                Author information
                https://orcid.org/0000-0002-9148-1094
                https://orcid.org/0000-0002-3866-8466
                https://orcid.org/0000-0002-0370-8640
                Article
                micromachines-10-00574
                10.3390/mi10090574
                6780249
                31480230
                4978a839-1839-473d-a9dc-e1f525706e18
                © 2019 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 29 July 2019
                : 29 August 2019
                Categories
                Article

                gas sensors,acetone detection,microwave application,uv illumination

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