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      Near infrared reflectance spectrometry classification of lettuce using linear discriminant analysis

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          Abstract

          This study proposes a methodology for lettuce classification employing near infrared reflectance spectrometry and variable selection.

          Abstract

          This study proposes a methodology for lettuce classification employing near infrared reflectance spectrometry and variable selection. For this purpose, genetic algorithm (GA), successive projections algorithm (SPA) and stepwise (SW) formulation were employed to choose reduced subset of variables (wavenumbers) for linear discriminant analysis (LDA) models. The proposed method was applied to a set of 104 lettuce samples of three different cultivation types (organic, hydroponic and conventional). The classification results of LDA/GA, LDA/SPA and LDA/SW models were assessed in terms of the correct classification rate (CCR) obtained for the test samples. The best results were found with LDA/GA models, achieving a CCR of 95.4% in the test set, whereas the LDA/SW and LDA/SPA models correctly classified at 77.3% and 68.2%, respectively. The results obtained in this investigation suggest that the proposed method is a promising alternative for the assessment of the authenticity of lettuce cultivation type.

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          Computer Aided Design of Experiments

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            Variables selection methods in near-infrared spectroscopy.

            Near-infrared (NIR) spectroscopy has increasingly been adopted as an analytical tool in various fields, such as the petrochemical, pharmaceutical, environmental, clinical, agricultural, food and biomedical sectors during the past 15 years. A NIR spectrum of a sample is typically measured by modern scanning instruments at hundreds of equally spaced wavelengths. The large number of spectral variables in most data sets encountered in NIR spectral chemometrics often renders the prediction of a dependent variable unreliable. Recently, considerable effort has been directed towards developing and evaluating different procedures that objectively identify variables which contribute useful information and/or eliminate variables containing mostly noise. This review focuses on the variable selection methods in NIR spectroscopy. Selection methods include some classical approaches, such as manual approach (knowledge based selection), "Univariate" and "Sequential" selection methods; sophisticated methods such as successive projections algorithm (SPA) and uninformative variable elimination (UVE), elaborate search-based strategies such as simulated annealing (SA), artificial neural networks (ANN) and genetic algorithms (GAs) and interval base algorithms such as interval partial least squares (iPLS), windows PLS and iterative PLS. Wavelength selection with B-spline, Kalman filtering, Fisher's weights and Bayesian are also mentioned. Finally, the websites of some variable selection software and toolboxes for non-commercial use are given. Copyright 2010 Elsevier B.V. All rights reserved.
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              Supervised pattern recognition in food analysis.

              Data analysis has become a fundamental task in analytical chemistry due to the great quantity of analytical information provided by modern analytical instruments. Supervised pattern recognition aims to establish a classification model based on experimental data in order to assign unknown samples to a previously defined sample class based on its pattern of measured features. The basis of the supervised pattern recognition techniques mostly used in food analysis are reviewed, making special emphasis on the practical requirements of the measured data and discussing common misconceptions and errors that might arise. Applications of supervised pattern recognition in the field of food chemistry appearing in bibliography in the last two years are also reviewed.
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                Author and article information

                Journal
                AMNECT
                Analytical Methods
                Anal. Methods
                Royal Society of Chemistry (RSC)
                1759-9660
                1759-9679
                2015
                2015
                : 7
                : 5
                : 1890-1895
                Article
                10.1039/C4AY02407A
                4a5ae44d-f7cb-430e-a834-2db4ff1bf536
                © 2015
                History

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