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      Micro solid oxide fuel cell fabricated on porous stainless steel: a new strategy for enhanced thermal cycling ability

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          Abstract

          Miniaturized solid oxide fuel cells (micro-SOFCs) are being extensively studied as a promising alternative to Li batteries for next generation portable power. A new micro-SOFC is designed and fabricated which shows enhanced thermal robustness by employing oxide-based thin-film electrode and porous stainless steel (STS) substrate. To deposit gas-tight thin-film electrolyte on STS, nano-porous composite oxide is proposed and applied as a new contact layer on STS. The micro-SOFC fabricated on composite oxide- STS dual layer substrate shows the peak power density of 560 mW cm −2 at 550 °C and maintains this power density during rapid thermal cycles. This cell may be suitable for portable electronic device that requires high power-density and fast thermal cycling.

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          In situ growth of nanoparticles through control of non-stoichiometry.

          Surfaces decorated with uniformly dispersed catalytically active nanoparticles play a key role in many fields, including renewable energy and catalysis. Typically, these structures are prepared by deposition techniques, but alternatively they could be made by growing the nanoparticles in situ directly from the (porous) backbone support. Here we demonstrate that growing nano-size phases from perovskites can be controlled through judicious choice of composition, particularly by tuning deviations from the ideal ABO3 stoichiometry. This non-stoichiometry facilitates a change in equilibrium position to make particle exsolution much more dynamic, enabling the preparation of compositionally diverse nanoparticles (that is, metallic, oxides or mixtures) and seems to afford unprecedented control over particle size, distribution and surface anchorage. The phenomenon is also shown to be influenced strongly by surface reorganization characteristics. The concept exemplified here may serve in the design and development of more sophisticated oxide materials with advanced functionality across a range of possible domains of application.
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            Review on microfabricated micro-solid oxide fuel cell membranes

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              Thermal, electrical, and electrocatalytical properties of lanthanum-doped strontium titanate

              O Marina (2002)
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                Author and article information

                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group
                2045-2322
                01 March 2016
                2016
                : 6
                : 22443
                Affiliations
                [1 ]Department of Materials Science and Engineering/Fuel Cell Research Center Pohang University of Science and Technology (POSTECH) , 77 Cheongamro, Nam-gu, Pohang, Gyeongbuk 37673, Republic of Korea
                [2 ]Research Institute of Industrial Science and Technology (RIST) Pohang 790-330, Republic of Korea
                Author notes
                Article
                srep22443
                10.1038/srep22443
                4772004
                26928921
                4b54c2c1-f559-4628-881a-081a1f8ae7cb
                Copyright © 2016, Macmillan Publishers Limited

                This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

                History
                : 07 December 2015
                : 15 February 2016
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