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      A feasible method to improve the protection ability of metal by functionalized carbon dots as environment-friendly corrosion inhibitor

      , , , ,
      Journal of Cleaner Production
      Elsevier BV

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          Blue luminescent graphene quantum dots and graphene oxide prepared by tuning the carbonization degree of citric acid

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            Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis.

            The electronic and chemical properties of graphene can be modulated by chemical doping foreign atoms and functional moieties. The general approach to the synthesis of nitrogen-doped graphene (NG), such as chemical vapor deposition (CVD) performed in gas phases, requires transitional metal catalysts which could contaminate the resultant products and thus affect their properties. In this paper, we propose a facile, catalyst-free thermal annealing approach for large-scale synthesis of NG using low-cost industrial material melamine as the nitrogen source. This approach can completely avoid the contamination of transition metal catalysts, and thus the intrinsic catalytic performance of pure NGs can be investigated. Detailed X-ray photoelectron spectrum analysis of the resultant products shows that the atomic percentage of nitrogen in doped graphene samples can be adjusted up to 10.1%. Such a high doping level has not been reported previously. High-resolution N1s spectra reveal that the as-made NG mainly contains pyridine-like nitrogen atoms. Electrochemical characterizations clearly demonstrate excellent electrocatalytic activity of NG toward the oxygen reduction reaction (ORR) in alkaline electrolytes, which is independent of nitrogen doping level. The present catalyst-free approach opens up the possibility for the synthesis of NG in gram-scale for electronic devices and cathodic materials for fuel cells and biosensors.
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              Evaluation of Ginkgo leaf extract as an eco-friendly corrosion inhibitor of X70 steel in HCl solution

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                Author and article information

                Journal
                Journal of Cleaner Production
                Journal of Cleaner Production
                Elsevier BV
                09596526
                August 2020
                August 2020
                : 264
                : 121682
                Article
                10.1016/j.jclepro.2020.121682
                4b85ad0d-58c0-494f-8f91-47fe59d279b5
                © 2020

                https://www.elsevier.com/tdm/userlicense/1.0/

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