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      Surface Characterizations of Fretting Fatigue Damage in Aluminum Alloy 7075-T6 Clamped Joints: The Beneficial Role of Ni–P Coatings

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          Abstract

          This paper aims to characterize the surface damage as a consequence of fretting fatigue in aluminum alloy 7075-T6 plates in double-lap bolted joints through XRD, surface profilometry, and SEM analyses. The main focus was on the surface roughness and chemical phase composition of the damaged zone along with the identification of fretting fatigue crack initiations over the surface of the material. The surface roughness of the fretted zone was found to increase when the joint was clamped with a higher tightening torque and tested under the same cyclic loading. Additionally, MgZn 2 (η/ή) precipitates and ZnO phase were found to form onto the surface of uncoated aluminum plate in the fretted and worn zones. The formation of the ZnO phase was understood to be a result of frictional heat induced between the surface of contacting uncoated Al 7075-T6 plates during cyclic loading and exposure to the air. The beneficial role of electroless nickel-phosphorous (Ni–P) coatings in minimizing the fretting damage and thus improving the fretting fatigue life of the aluminum plates was also studied. The results showed that the surface roughness decreased by approximately 40% after applying Ni–P coatings to the Al 7075-T6 plates.

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          Synthetic levers enabling independent control of phase, size, and morphology in nickel phosphide nanoparticles.

          Simultaneous control of phase, size, and morphology in nanoscale nickel phosphides is reported. Phase-pure samples of discrete nanoparticles of Ni12P5 and Ni2P in hollow and solid morphologies can be prepared in a range of sizes (10-32 nm) by tuning key interdependent synthetic levers (P:Ni precursor ratio, temperature, time, oleylamine quantity). Size and morphology are controlled by the P:Ni ratio in the synthesis of the precursor particles, with large, hollow particles formed at low P:Ni and small, solid particles formed at high P:Ni. The P:Ni ratio also impacts the phase at the crystallization temperature (300-350 °C), with metal-rich Ni12P5 generated at low P:Ni and Ni2P at high P:Ni. Moreover, the product phase formed can be decoupled from the initial precursor ratio by the addition of more "P" at the crystallization temperature. This enables formation of hollow particles (favored by low P:Ni) of Ni2P (favored by high P:Ni). Increasing temperature and time also favor formation of Ni2P, by generating more reactive P and providing sufficient time for conversion to the thermodynamic product. Finally, increasing oleylamine concentration allows Ni12P5 to be obtained under high P:Ni precursor ratios that favor solid particle formation. Oleylamine concentration also acts to "tune" the size of the voids in particles formed at low P:Ni ratios, enabling access to Ni12P5 particles with different void sizes. This approach enables an unprecedented level of control over phase and morphology of nickel phosphide nanoparticles, paving the way for systematic investigation of the impact of these parameters on hydrodesulfurization activities of nickel phosphides.
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            Nickel Phosphide Nanoparticles with Hollow, Solid, and Amorphous Structures

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              Mechanics of fretting fatigue crack formation

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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                27 February 2016
                March 2016
                : 9
                : 3
                : 141
                Affiliations
                [1 ]Discipline of Mechanical Engineering, School of Computer Science, Engineering and Mathematics, Flinders University, Clovelly Park SA 5042, Australia; mohammad.barati@ 123456flinders.edu.au
                [2 ]Department of Mechanical & Aerospace Engineering, Monash University, Clayton VIC 3800, Australia; raafat.ibrahim@ 123456monash.edu
                [3 ]Department of Materials Science and Engineering, Monash University, Clayton VIC 3800, Australia
                Author notes
                [* ]Correspondence: reza.oskouei@ 123456flinders.edu.au ; Tel.: +61-8-8201-2782; Fax: +61-8-8201-2904
                Article
                materials-09-00141
                10.3390/ma9030141
                5456715
                4ffac3c8-3086-45df-b5a4-874b23cad0a1
                © 2016 by the authors;

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 14 November 2015
                : 23 February 2016
                Categories
                Article

                fretting fatigue,aluminum alloys,ni–p coatings,surface roughness,clamped joints

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