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      Designing thermoelectric generators for self-powered wearable electronics

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          Abstract

          Computational efficient, quasi-3D model for designing body wearable thermoelectric generators and experimental verification.

          Abstract

          Body wearable sensors and electronics for health and environment monitoring are becoming increasingly popular as their functionality increases. Thermoelectric generators (TEGs) are of interest to make these wearables self-powered by making them rely entirely on the heat harvested from the human body. The challenge with using thermoelectrics on the human body is the large thermal resistances experienced at the skin/TEG and TEG/ambient interfaces. These parasitics can be potentially so large that they can dominate the device performance. Therefore, it is critical to have accurate models to predict the device performance considering material properties, module design and parasitics. In this paper, we present a computationally efficient, quasi three-dimensional TEG model and use this model to explore the design criteria for current state-of-the-art rigid TEG modules as well as prospective flexible modules for body wearable applications. We show the impact of the properties of the thermoelectric material, module design and dimensions, heat spreaders, filler material, heat sink and skin contact resistance on device performance. We also identify the significance of material thermal conductivity over the Seebeck coefficient and electrical resistivity in improving the output power for wearable applications. For flexible TEGs, we identify the thermal conductivity of the filler material as one of the critical parameters that need to be taken into consideration for optimal performance. Finally, the model was used to design a custom TEG with improved material properties and device design. The measurements indicate a nearly 3× improvement in power output over a commercial TEG with similar area as successfully predicted by the calculations.

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          Complex thermoelectric materials.

          Thermoelectric materials, which can generate electricity from waste heat or be used as solid-state Peltier coolers, could play an important role in a global sustainable energy solution. Such a development is contingent on identifying materials with higher thermoelectric efficiency than available at present, which is a challenge owing to the conflicting combination of material traits that are required. Nevertheless, because of modern synthesis and characterization techniques, particularly for nanoscale materials, a new era of complex thermoelectric materials is approaching. We review recent advances in the field, highlighting the strategies used to improve the thermopower and reduce the thermal conductivity.
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            Optimization of the thermoelectric figure of merit in the conducting polymer poly(3,4-ethylenedioxythiophene).

            Thermoelectric generators (TEGs) transform a heat flow into electricity. Thermoelectric materials are being investigated for electricity production from waste heat (co-generation) and natural heat sources. For temperatures below 200 °C, the best commercially available inorganic semiconductors are bismuth telluride (Bi(2)Te(3))-based alloys, which possess a figure of merit ZT close to one. Most of the recently discovered thermoelectric materials with ZT>2 exhibit one common property, namely their low lattice thermal conductivities. Nevertheless, a high ZT value is not enough to create a viable technology platform for energy harvesting. To generate electricity from large volumes of warm fluids, heat exchangers must be functionalized with TEGs. This requires thermoelectric materials that are readily synthesized, air stable, environmentally friendly and solution processable to create patterns on large areas. Here we show that conducting polymers might be capable of meeting these demands. The accurate control of the oxidation level in poly(3,4-ethylenedioxythiophene) (PEDOT) combined with its low intrinsic thermal conductivity (λ=0.37 W m(-1) K(-1)) yields a ZT=0.25 at room temperature that approaches the values required for efficient devices. © 2011 Macmillan Publishers Limited. All rights reserved
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              Engineered doping of organic semiconductors for enhanced thermoelectric efficiency.

              Significant improvements to the thermoelectric figure of merit ZT have emerged in recent years, primarily due to the engineering of material composition and nanostructure in inorganic semiconductors (ISCs). However, many present high-ZT materials are based on low-abundance elements that pose challenges for scale-up, as they entail high material costs in addition to brittleness and difficulty in large-area deposition. Here we demonstrate a strategy to improve ZT in conductive polymers and other organic semiconductors (OSCs) for which the base elements are earth-abundant. By minimizing total dopant volume, we show that all three parameters constituting ZT vary in a manner so that ZT increases; this stands in sharp contrast to ISCs, for which these parameters have trade-offs. Reducing dopant volume is found to be as important as optimizing carrier concentration when maximizing ZT in OSCs. Implementing this strategy with the dopant poly(styrenesulphonate) in poly(3,4-ethylenedioxythiophene), we achieve ZT  =  0.42 at room temperature.
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                Author and article information

                Journal
                EESNBY
                Energy & Environmental Science
                Energy Environ. Sci.
                Royal Society of Chemistry (RSC)
                1754-5692
                1754-5706
                2016
                2016
                : 9
                : 6
                : 2099-2113
                Affiliations
                [1 ]Department of Electrical and Computer Engineering
                [2 ]North Carolina State University
                [3 ]Raleigh
                [4 ]USA
                Article
                10.1039/C6EE00456C
                5609e12b-bdcd-434b-ae36-6fa278f53c76
                © 2016
                History

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