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Coordination Modes of a Schiff Base Derived from Substituted 2-Aminothiazole with Chromium(III), Manganese(II), Iron(II), Cobalt(II), Nickel(II) and Copper(II) Metal Ions: Synthesis, Spectroscopic and Antimicrobial Studies

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      Abstract

      Transition metal complexes of Cr(III), Mn(II), Fe(II), Co(II), Ni(II) and Cu(II) metal ions with general stoichiometry [ML 2.2H 2O] and [ML 3], where M= Mn(II), Cr(III), Fe(II), Co(II), Ni(II) and Cu(II), L= Schiff base derived from the condensation of 2-amino-4(4’-phenyl/methylphenyl)-5-methyl-thiazole with 4-acetyl-1(3-chloro phenyl)-3-methyl-2-pyrazoline-5-ones, have been synthesized and structurally characterized by elemental analysis, molar conductance measurements, magnetic susceptibility measurements and spectral techniques like IR, UV, 1H NMR, 13C NMR and Mass Spectra. All the complexes were found to be octahedral geometry. The ligand and its complexes have been screened for their antifungal and antibacterial activities against three fungi, i.e. Alternaria brassicae, Aspergillus nigerand Fesarium oxysporumand two bacteria, i.e. Xanthomonas compestrisand Pseudomonas aeruginosa.

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      The synthesis of 2,3-disubstituted-4-thiazolidones.

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        Transition metal complexes with uninegative bidentate Schiff base

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          Author and article information

          Journal
          E-Journal of Chemistry
          E-Journal of Chemistry
          Hindawi Limited
          0973-4945
          2090-9810
          2011
          2011
          : 8
          : 4
          : 1750-1764
          10.1155/2011/282061
          © 2011

          http://creativecommons.org/licenses/by/3.0/

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