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      Mean-field theory of active electrolytes: Dynamic adsorption and overscreening

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      Physical Review E

      American Physical Society (APS)

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          Active Particles in Complex and Crowded Environments

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            Clustering and relaxation in Hamiltonian long-range dynamics

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              Is Open Access

              Steric Effects in Electrolytes: A Modified Poisson-Boltzmann Equation

              The adsorption of large ions from solution to a charged surface is investigated theoretically. A generalized Poisson--Boltzmann equation, which takes into account the finite size of the ions is presented. We obtain analytical expressions for the electrostatic potential and ion concentrations at the surface, leading to a modified Grahame equation. At high surface charge densities the ionic concentration saturates to its maximum value. Our results are in agreement with recent experiments.
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                Author and article information

                Journal
                PLEEE8
                Physical Review E
                Phys. Rev. E
                American Physical Society (APS)
                2470-0045
                2470-0053
                May 2018
                May 14 2018
                : 97
                : 5
                Article
                10.1103/PhysRevE.97.052609
                © 2018

                https://link.aps.org/licenses/aps-default-license

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