Hemilabile P,N-Ligand-Assisted Gold-Catalyzed Heck Reaction of Aryl and Styryl Iodides with Styrenes.

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Abstract

A gold-catalyzed Heck reaction of aryl and styryl iodides with styrenes was developed. The hemilabile P,N-ligand-assisted gold-catalyzed C(sp2)-C(sp2) cross-coupling can synthesize stilbenes and bistyryl complexes, with good functional-group tolerance and mild conditions. The elementary organometallic steps of migratory insertion and β-hydride elimination might be involved in this ligand-enabled Au(I)/Au(III)-catalyzed Heck reaction with styrenes.

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Journal

Journal ID (iso-abbrev): Org Lett

Title: Organic letters

Publisher: American Chemical Society (ACS)

ISSN (Electronic): 1523-7052

ISSN (Print): 1523-7052

Publication date (Electronic): Sep 22 2023

Volume: 25

Issue: 37

Affiliations

[1 ] School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.

Article

DOI: 10.1021/acs.orglett.3c02244

PubMed ID: 37690122

SO-VID: 5b66ba0a-2e7a-4bcc-9d60-5d0731b37067

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