- Record: found
- Abstract: found
- Article: not found
Scalable procedure for the fragmentation of hydroperoxides mediated by copper and iron tetrafluoroborate salts
David Huang
1
,
2
,
3
,
4 ,
Alexander W. Schuppe
1
,
2
,
3
,
4 ,
Michael Z. Liang
1
,
2
,
3
,
4 ,
Timothy R. Newhouse
1
,
2
,
3
,
4
2016
Read this article at
There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.
Abstract
An improved protocol for the formal elimination of propene from organic substrates is reported.
Abstract
An improved protocol for the formal elimination of propene from organic substrates is reported. This process entails the ozonolytic conversion of an alkene to a methoxy hydroperoxide which undergoes fragmentation mediated by copper and iron. The use of soluble Cu(BF 4) 2 and Fe(BF 4) 2 results in reproducible results up to a 100 gram scale.
Related collections
Most cited references36
- Record: found
- Abstract: not found
- Article: not found
Synthesis of .alpha.,.beta.-unsaturated carbonyl compounds by palladium(II)-catalyzed dehydrosilylation of silyl enol ethers
Yoshihiko Ito, Toshikazu Hirao, Takeo Saegusa (1978)
- Record: found
- Abstract: not found
- Article: not found
Organoselenium chemistry. Conversion of ketones to enones by selenoxide syn elimination
Hans Reich, James M Renga, Ieva Reich (1975)
- Record: found
- Abstract: not found
- Article: not found
Formation of remote double bonds by ferrous sulfate-cupric acetate promoted decomposition of alkyl hydroperoxides
Ẑivorad Čeković, Mark M. Green (1974)