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      Fabrication and Characteristics of SnAgCu Alloy Nanowires for Electrical Connection Application

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          Abstract

          As electronic products become more functional, the devices are required to provide better performances and meet ever smaller form factor requirements. To achieve a higher I/O density within the smallest form factor package, applying nanotechniques to electronic packaging can be regarded as a possible approach in microelectronic technology. Sn-3.0 wt% Ag-0.5 wt% Cu (SAC305) is a common solder material of electrical connections in microelectronic devices. In this study, SAC305 alloy nanowire was fabricated in a porous alumina membrane with a pore diameter of 50 nm by the pressure casting method. The crystal structure and composition analyses of SAC305 nanowires show that the main structure of the nanowire is β-Sn, and the intermetallic compound, Ag 3Sn, locates randomly but always appears on the top of the nanowire. Furthermore, differential scanning calorimetry (DSC) results indicate the melting point of SAC305 alloy nanowire is around 227.7 °C. The melting point of SAC305 alloy nanowire is significantly higher than that of SAC305 bulk alloy (219.4 °C). It is supposed that the non-uniform phase distribution and composite difference between the nanowires causes the change of melting temperature.

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          Most cited references23

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          Reliability challenges in 3D IC packaging technology

          K.N Tu (2011)
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            Modelling for size-dependent and dimension-dependent melting of nanocrystals

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              Superplastic nanoscale pore shaping by ion irradiation

              Exposed to ionizing radiation, nanomaterials often undergo unusual transformations compared to their bulk form. However, atomic-level mechanisms of such transformations are largely unknown. This work visualizes and quantifies nanopore shrinkage in nanoporous alumina subjected to low-energy ion beams in a helium ion microscope. Mass transport in porous alumina is thus simultaneously induced and imaged with nanoscale precision, thereby relating nanoscale interactions to mesoscopic deformations. The interplay between chemical bonds, disorders, and ionization-induced transformations is analyzed. It is found that irradiation-induced diffusion is responsible for mass transport and that the ionization affects mobility of diffusive entities. The extraordinary room temperature superplasticity of the normally brittle alumina is discovered. These findings enable the effective manipulation of chemical bonds and structural order by nanoscale ion-matter interactions to produce mesoscopic structures with nanometer precision, such as ultra-high density arrays of sub-10-nm pores with or without the accompanying controlled plastic deformations.
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                Author and article information

                Journal
                Micromachines (Basel)
                Micromachines (Basel)
                micromachines
                Micromachines
                MDPI
                2072-666X
                05 December 2018
                December 2018
                : 9
                : 12
                : 644
                Affiliations
                [1 ]Department of Industrial Education, National Taiwan Normal University, 106 Taipei, Taiwan
                [2 ]Department of Electron Microscopy Development Application, Industrial Technology Research Institute, 310 Hsinchu, Taiwan; SCLo@ 123456itri.org.tw (S.-C.L.); itri4907@ 123456itri.org.tw (S.-C.H.)
                [3 ]Department of Mechanical Engineering, Lunghwa University of Science and Technology, 333 Taoyuan, Taiwan
                Author notes
                [* ]Correspondence: jhchen@ 123456ntnu.edu.tw (J.-H.C.); cyhsu@ 123456mail.lhu.edu.tw (C.-Y.H.)
                Article
                micromachines-09-00644
                10.3390/mi9120644
                6316273
                30563062
                5e2f605a-03c8-4499-b53a-dfdb2713419c
                © 2018 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 15 November 2018
                : 03 December 2018
                Categories
                Article

                sac305,solder,nanowires,intermetallic compound,electrical connection

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