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      Experimental Observation of Lee-Yang Zeros

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          Abstract

          Lee-Yang zeros are points on the complex plane of physical parameters where the partition function of a system vanishes and hence the free energy diverges. Lee-Yang zeros are ubiquitous in many-body systems and fully characterize their thermodynamics. Notwithstanding their fundamental importance, Lee-Yang zeros have never been observed in experiments, due to the intrinsic difficulty that they would occur only at complex values of physical parameters, which are generally regarded as unphysical. Here we report the first observation of Lee-Yang zeros, by measuring quantum coherence of a probe spin coupled to an Ising-type spin bath. The quantum evolution of the probe spin introduces a complex phase factor and therefore effectively realizes an imaginary magnetic field. From the measured Lee-Yang zeros, we reconstructed the free energy of the spin bath and determined its phase transition temperature. This experiment opens up new opportunities of studying thermodynamics in the complex plane.

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          Statistical Theory of Equations of State and Phase Transitions. II. Lattice Gas and Ising Model

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            Statistical Theory of Equations of State and Phase Transitions. I. Theory of Condensation

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              Free energy reconstruction from nonequilibrium single-molecule pulling experiments.

              Laser tweezers and atomic force microscopes are increasingly used to probe the interactions and mechanical properties of individual molecules. Unfortunately, using such time-dependent perturbations to force rare molecular events also drives the system away from equilibrium. Nevertheless, we show how equilibrium free energy profiles can be extracted rigorously from repeated nonequilibrium force measurements on the basis of an extension of Jarzynski's remarkable identity between free energies and the irreversible work.
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                Author and article information

                Journal
                PRLTAO
                Physical Review Letters
                Phys. Rev. Lett.
                American Physical Society (APS)
                0031-9007
                1079-7114
                January 2015
                January 5 2015
                : 114
                : 1
                Article
                10.1103/PhysRevLett.114.010601
                25615455
                5fbb9a00-4fdd-432f-806e-0798cdf334eb
                © 2015

                http://link.aps.org/licenses/aps-default-license

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