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      Reevaluating carbon fluxes in subduction zones, what goes down, mostly comes up

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      Proceedings of the National Academy of Sciences
      Proceedings of the National Academy of Sciences

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          Abstract

          Carbon fluxes in subduction zones can be better constrained by including new estimates of carbon concentration in subducting mantle peridotites, consideration of carbonate solubility in aqueous fluid along subduction geotherms, and diapirism of carbon-bearing metasediments. Whereas previous studies concluded that about half the subducting carbon is returned to the convecting mantle, we find that relatively little carbon may be recycled. If so, input from subduction zones into the overlying plate is larger than output from arc volcanoes plus diffuse venting, and substantial quantities of carbon are stored in the mantle lithosphere and crust. Also, if the subduction zone carbon cycle is nearly closed on time scales of 5-10 Ma, then the carbon content of the mantle lithosphere + crust + ocean + atmosphere must be increasing. Such an increase is consistent with inferences from noble gas data. Carbon in diamonds, which may have been recycled into the convecting mantle, is a small fraction of the global carbon inventory.

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          Most cited references108

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          The chemical composition of subducting sediment and its consequences for the crust and mantle

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            The global range of subduction zone thermal models

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              Serpentine stability to mantle depths and subduction-related magmatism.

              Results of high-pressure experiments on samples of hydrated mantle rocks show that the serpentine mineral antigorite is stable to approximately 720 degrees C at 2 gigapascals, to approximately 690 degrees C at 3 gigapascals, and to approximately 620 degrees C at 5 gigapascals. The breakdown of antigorite to forsterite plus enstatite under these conditions produces 13 percent H(2)O by weight to depths of 150 to 200 kilometers in subduction zones. This H(2)O is in an ideal position for ascent into the hotter, overlying mantle where it can cause partial melting in the source region for calc-alkaline magmas at a depth of 100 to 130 kilometers and a temperature of approximately 1300 degrees C. The breakdown of antigorite in hydrated mantle produces an order of magnitude more H(2)O than does the dehydration of altered oceanic crust.
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                Author and article information

                Journal
                Proceedings of the National Academy of Sciences
                Proc Natl Acad Sci USA
                Proceedings of the National Academy of Sciences
                0027-8424
                1091-6490
                July 28 2015
                July 28 2015
                July 28 2015
                June 05 2015
                : 112
                : 30
                : E3997-E4006
                Article
                10.1073/pnas.1507889112
                4522802
                26048906
                603cebf5-b4ec-4a83-bb91-0b062803b6e9
                © 2015
                History

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