A novel dinuclear tetracarbonyl complex containing a bridging alkyldiazenido ligand [WCl(CO)2(PMe2Ph)2(NNCMe2CMe2NN)WCl(CO)2(PMe2Ph)2] formed via a cationic carbonyldiazoalkane complex [WCl(CO)(NNCMe2)(PMe2Ph)3][ZnCl3(thf)]
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