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      Ionic Liquids as Advanced Lubricant Fluids

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          Abstract

          Ionic liquids (ILs) are finding technological applications as chemical reaction media and engineering fluids. Some emerging fields are those of lubrication, surface engineering and nanotechnology. ILs are thermally stable, non-flammable highly polar fluids with negligible volatility, these characteristics make them ideal candidates for new lubricants under severe conditions, were conventional oils and greases or solid lubricants fail. Such conditions include ultra-high vacuum and extreme temperatures. Other very promising areas which depend on the interaction between IL molecules and material surfaces are the use of ILs in the lubrication of microelectromechanic and nanoelectromechanic systems (MEMS and NEMS), the friction and wear reduction of reactive light alloys and the modification of nanophases.

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          Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids

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            Dialkylimidazolium chloroaluminate melts: a new class of room-temperature ionic liquids for electrochemistry, spectroscopy and synthesis

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              Ionic liquid lubricants: designed chemistry for engineering applications.

              This tutorial review outlines current state of the art research on ionic liquid lubricants. Ionic liquids (ILs) were first reported as very promising high-performance lubricants in 2001 and have attracted considerable attention in the field of tribology since then because of their remarkable lubrication and anti-wear capabilities as compared with lubrication oils in general use; in recent times we have seen dramatically increased interest in the topic. The review starts with a brief introduction to ILs and fluid lubrication, and then discusses in more detail the tribological properties of IL lubricants, either as lubrication oils, additives or thin films. As well as lubrication mechanisms, some current problems and potential solutions are tentatively discussed.
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                Author and article information

                Journal
                Molecules
                Molecules
                molecules
                Molecules
                Molecular Diversity Preservation International
                1420-3049
                04 August 2009
                August 2009
                : 14
                : 8
                : 2888-2908
                Affiliations
                Grupo de Ciencia de Materiales e Ingeniería Metalúrgica, Departamento de Ingeniería de Materiales y Fabricación, Universidad Politécnica de Cartagena, Campus Muralla del Mar. 30202-Cartagena, Spain
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: mdolores.bermudez@ 123456upct.es
                Article
                molecules-14-02888
                10.3390/molecules14082888
                6255031
                19701132
                6714ad12-baca-4829-b916-dd59a7b1352e
                © 2009 by the authors;

                licensee Molecular Diversity Preservation International, Basel, Switzerland. This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/).

                History
                : 17 July 2009
                : 30 July 2009
                : 03 August 2009
                Categories
                Review

                ionic liquids,surface interactions,tribochemistry,additives,nanotechnology

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