Controlling Molecular Ordering in Aqueous Conducting Polymers Using Ionic Liquids

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Abstract

<p class="first" id="d14359394e143">The molecular ordering of aqueous conducting polymers is controlled using a rational method. By introducing various ionic liquids, which have designed electrostatic interactions to PEDOT:PSS solutions, the evolution of the molecular ordering of the PEDOT is manipulated. Consequently, highly ordered nanostructures are achieved with a reduced π-π stacking distance of ≈3.38 Å and, thus, a maximum σdc of ≈2100 S cm-1 . </p>

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Journal

Title: Advanced Materials

Abbreviated Title: Adv. Mater.

Publisher: Wiley

ISSN: 09359648

Publication date Created: October 2016

Publication date (Print): October 2016

Publication date (Electronic): August 08 2016

Volume: 28

Issue: 39

Pages: 8625-8631

Affiliations

[1 ]School of Materials Science and Engineering and Department of Nanobio Materials and Electronics; Heeger Center for Advanced Materials and Research Institute for Solar and Sustainable Energies; Gwangju Institute of Science and Technology; Gwangju 500-712 Republic of Korea

[2 ]Pohang Accelerator Laboratory; Pohang University of Science and Technology; Pohang 790-784 Republic of Korea

Article

DOI: 10.1002/adma.201505473

PubMed ID: 27501437

SO-VID: 69005269-07be-4df3-93ae-091d8e1c5f46

License:

http://doi.wiley.com/10.1002/tdm_license_1.1

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