Fifteen polycyclic aromatic hydrocarbons (PAHs) in 41 surface sediment samples and a sediment core (50 cm) from the Beibu Gulf, a significant low-latitude developing gulf, were analyzed. PAHs concentrations were 3.01-388 ng g(-)(1) (mean 95.5 ng g(-)(1)) in the surface sediments and 10.5-87.1 ng g(-)(1) (average 41.1 ng g(-)(1)) in the sediment core. Source apportionment indicated that PAHs were generated from coke production and vehicular emissions (39.4%), coal and biomass combustion (35.8%), and petrogenic sources (24.8%). PAHs were mainly concentrated in the industrialized and urbanized regions and the harbor, and were transported by atmospheric deposition to the marine matrix. The mass inventory (1.57-2.62t) and probability risk showed sediments here served as an important reservoir but low PAH risk. Different from oil and natural gas in developed regions, coal combustion has always been a significant energy consumption pattern in this developing region for the past 30 years (56 ± 5%).