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      Fe 1−xS Modified TiO 2 NPs Embedded Carbon Nanofiber Composite via Electrospinning: A Potential Electrode Material for Supercapacitors

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      1 , 2 , 1 , *
      Molecules
      MDPI
      Fe1−xS-TiO2, carbon nanofibers, composite, electrospinning, energy storage

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          Abstract

          Fe 1−xS-TiO 2 nanoparticles embedded carbon nanofibers (Fe 1−xS-TiO 2/CNFs) composite as a supercapacitor electrode material has been reported in the present work. The Fe 1−xS-TiO 2/CNFs composite was fabricated by electrospinning technique followed by carbonization under argon atmosphere and characterized by the state-of-art techniques. The electrochemical studies were carried out in a 2 M KOH electrolyte solution. The synthesized material showed a specific capacitance value of 138 F/g at the current density of 1 A/g. Further, the capacitance retention was about 83%. The obtained results indicate that the Fe 1−xS-TiO 2/CNFs composite can be recognized as electrode material in supercapacitor.

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          Most cited references41

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          Nanostructured metal sulfides for energy storage.

          Advanced electrodes with a high energy density at high power are urgently needed for high-performance energy storage devices, including lithium-ion batteries (LIBs) and supercapacitors (SCs), to fulfil the requirements of future electrochemical power sources for applications such as in hybrid electric/plug-in-hybrid (HEV/PHEV) vehicles. Metal sulfides with unique physical and chemical properties, as well as high specific capacity/capacitance, which are typically multiple times higher than that of the carbon/graphite-based materials, are currently studied as promising electrode materials. However, the implementation of these sulfide electrodes in practical applications is hindered by their inferior rate performance and cycling stability. Nanostructures offering the advantages of high surface-to-volume ratios, favourable transport properties, and high freedom for the volume change upon ion insertion/extraction and other reactions, present an opportunity to build next-generation LIBs and SCs. Thus, the development of novel concepts in material research to achieve new nanostructures paves the way for improved electrochemical performance. Herein, we summarize recent advances in nanostructured metal sulfides, such as iron sulfides, copper sulfides, cobalt sulfides, nickel sulfides, manganese sulfides, molybdenum sulfides, tin sulfides, with zero-, one-, two-, and three-dimensional morphologies for LIB and SC applications. In addition, the recently emerged concept of incorporating conductive matrices, especially graphene, with metal sulfide nanomaterials will also be highlighted. Finally, some remarks are made on the challenges and perspectives for the future development of metal sulfide-based LIB and SC devices.
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            Advanced materials and technologies for hybrid supercapacitors for energy storage – A review

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              A Ternary Fe1− x S@Porous Carbon Nanowires/Reduced Graphene Oxide Hybrid Film Electrode with Superior Volumetric and Gravimetric Capacities for Flexible Sodium Ion Batteries

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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Molecules
                Molecules
                molecules
                Molecules
                MDPI
                1420-3049
                27 February 2020
                March 2020
                : 25
                : 5
                : 1075
                Affiliations
                [1 ]Department of Biomedical Sciences and Institute for Medical Science, Jeonbuk National University Medical School, Chonbuk 54907, Korea; bisup@ 123456jbnu.ac.kr
                [2 ]Department of Applied Sciences, Tribhuvan University, Kathmandu 44600, Nepal; hempant@ 123456ioe.edu.np
                Author notes
                Article
                molecules-25-01075
                10.3390/molecules25051075
                7179207
                32121021
                6caaac71-cf1a-4db3-a1d0-77d862023791
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 07 January 2020
                : 26 February 2020
                Categories
                Article

                fe1−xs-tio2,carbon nanofibers,composite,electrospinning,energy storage

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