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      INTERFACIAL OXIDE LAYERS AT THE METAL–OXIDE PHASE BOUNDARY

      Surface Review and Letters
      World Scientific Pub Co Pte Lt

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          Strong metal-support interactions

          S Tauster (2002)
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            Strong interactions in supported-metal catalysts.

            Many commercially important catalysts consist of small metal particles dispersed on inorganic oxide surfaces. Although in most cases there is no significant interaction between the metal and the support, strong bonding can be demonstrated in a recently discovered class of supported-metal catalysts. These cases typically involve group VIII metals dispersed on transition metal oxides whose surfaces can be reduced to form cations with lower valences. Spectroscopic measurements indicate that an electron is transferred from the cation (such as Ti(3+) or Nb(4+)) to the metal particle. This, in turn, leads to profound changes in the catalytic and chemisorption properties and the morphology of the metal particles.
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              Metal deposits on well-ordered oxide films

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                Author and article information

                Journal
                Surface Review and Letters
                Surf. Rev. Lett.
                World Scientific Pub Co Pte Lt
                0218-625X
                1793-6667
                June 2002
                June 2002
                : 09
                : 03n04
                : 1553-1563
                Article
                10.1142/S0218625X02003950
                6ead260a-a6ee-4c9f-92ad-7b862cbfe73d
                © 2002
                History

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