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      40 Jahre Mukaiyama‐Aldolreaktion: eine Erfolgsgeschichte

      1 , 2
      Angewandte Chemie
      Wiley

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          Most cited references103

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          Asymmetric enamine catalysis.

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            The direct catalytic asymmetric aldol reaction.

            Asymmetric aldol reactions are a powerful method for the construction of carbon-carbon bonds in an enantioselective fashion. Historically this reaction has been performed in a stoichiometric fashion to control the various aspects of chemo-, diastereo-, regio- and enantioselectivity, however, a more atom economical approach would unite high selectivity with the use of only a catalytic amount of a chiral promoter. This critical review documents the development of direct catalytic asymmetric aldol methodologies, including organocatalytic and metal-based strategies. New methods have improved the reactivity, selectivity and substrate scope of the direct aldol reaction and enabled the synthesis of complex molecular targets (357 references).
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              Enantioselective aldol condensations. 2. Erythro-selective chiral aldol condensations via boron enolates

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                Author and article information

                Journal
                Angewandte Chemie
                Angew. Chem.
                Wiley
                0044-8249
                1521-3757
                July 2013
                August 26 2013
                July 23 2013
                August 26 2013
                : 125
                : 35
                : 9280-9289
                Affiliations
                [1 ]Division of Pharmaceutical Sciences, Graduate School of Medical Sciences, Kanazawa University, Kanazawa 920‐1192 (Japan)
                [2 ]Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615‐8510 (Japan) http://www.sbchem.kyoto‐u.ac.jp/murakami‐lab/
                Article
                10.1002/ange.201303192
                71f320b7-6ecc-4a57-a94b-a55a26d13279
                © 2013

                http://onlinelibrary.wiley.com/termsAndConditions#vor

                http://doi.wiley.com/10.1002/tdm_license_1.1

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