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      Ballistic tracks in graphene nanoribbons

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          Abstract

          High quality graphene nanoribbons epitaxially grown on the sidewalls of silicon carbide (SiC) mesa structures stand as key building blocks for graphene-based nanoelectronics. Such ribbons display 1D single-channel ballistic transport at room temperature with exceptionally long mean free paths. Here, using spatially-resolved two-point probe (2PP) measurements, we selectively access and directly image a range of individual transport modes in sidewall ribbons. The signature of the independently contacted channels is a sequence of quantised conductance plateaus for different probe positions. These result from an interplay between edge magnetism and asymmetric terminations at opposite ribbon edges due to the underlying SiC structure morphology. Our findings demonstrate a precise control of transport through multiple, independent, ballistic tracks in graphene-based devices, opening intriguing pathways for quantum information device concepts.

          Abstract

          Electronic highways were realized by means of epitaxially grown graphene nanoribbons on SiC substrates. Here, the authors use spatially-resolved two-point probe and conductive AFM measurements, supplemented by tight-binding calculations, to image the one-dimensional ballistic transport channels.

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          Longitudinal unzipping of carbon nanotubes to form graphene nanoribbons.

          Graphene, or single-layered graphite, with its high crystallinity and interesting semimetal electronic properties, has emerged as an exciting two-dimensional material showing great promise for the fabrication of nanoscale devices. Thin, elongated strips of graphene that possess straight edges, termed graphene ribbons, gradually transform from semiconductors to semimetals as their width increases, and represent a particularly versatile variety of graphene. Several lithographic, chemical and synthetic procedures are known to produce microscopic samples of graphene nanoribbons, and one chemical vapour deposition process has successfully produced macroscopic quantities of nanoribbons at 950 degrees C. Here we describe a simple solution-based oxidative process for producing a nearly 100% yield of nanoribbon structures by lengthwise cutting and unravelling of multiwalled carbon nanotube (MWCNT) side walls. Although oxidative shortening of MWCNTs has previously been achieved, lengthwise cutting is hitherto unreported. Ribbon structures with high water solubility are obtained. Subsequent chemical reduction of the nanoribbons from MWCNTs results in restoration of electrical conductivity. These early results affording nanoribbons could eventually lead to applications in fields of electronics and composite materials where bulk quantities of nanoribbons are required.
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            Half-Metallic Graphene Nanoribbons

            Electrical current can be completely spin polarized in a class of materials known as half-metals, as a result of the coexistence of metallic nature for electrons with one spin orientation and insulating for electrons with the other. Such asymmetric electronic states for the different spins have been predicted for some ferromagnetic metals - for example, the Heusler compounds- and were first observed in a manganese perovskite. In view of the potential for use of this property in realizing spin-based electronics, substantial efforts have been made to search for half-metallic materials. However, organic materials have hardly been investigated in this context even though carbon-based nanostructures hold significant promise for future electronic device. Here we predict half-metallicity in nanometre-scale graphene ribbons by using first-principles calculations. We show that this phenomenon is realizable if in-plane homogeneous electric fields are applied across the zigzag-shaped edges of the graphene nanoribbons, and that their magnetic property can be controlled by the external electric fields. The results are not only of scientific interests in the interplay between electric fields and electronic spin degree of freedom in solids but may also open a new path to explore spintronics at nanometre scale, based on graphene.
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              Peculiar Localized State at Zigzag Graphite Edge

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                Author and article information

                Contributors
                christoph.tegenkamp@physik.tu-chemnitz.de
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                24 October 2018
                24 October 2018
                2018
                : 9
                : 4426
                Affiliations
                [1 ]ISNI 0000 0001 2294 5505, GRID grid.6810.f, Institut für Physik, , Technische Universität Chemnitz, ; 09126 Chemnitz, Germany
                [2 ]GRID grid.7080.f, Catalan Institute of Nanoscience and Nanotechnology (ICN2), , CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, ; 08193 Barcelona (Cerdanyola del Vallès), Spain
                [3 ]GRID grid.7080.f, Universitat Autònoma de Barcelona, ; 08193 Bellaterra (Cerdanyola del Vallès), Spain
                [4 ]ISNI 0000 0004 1936 9705, GRID grid.8217.c, School of Physics, , Trinity College Dublin, ; Dublin, 2 Ireland
                [5 ]ISNI 0000 0004 0399 8953, GRID grid.6214.1, Physics of Interfaces and Nanomaterials, MESA+Institute for Nanotechnology, , University of Twente, ; 7522 NH Enschede, The Netherlands
                [6 ]ISNI 0000 0001 2163 2777, GRID grid.9122.8, Institut für Festkörperphysik, , Leibniz Universität Hannover, ; 30167 Hannover, Germany
                [7 ]ISNI 0000 0000 9601 989X, GRID grid.425902.8, ICREA, Institució Catalana de Recerca i Estudis Avançats, ; 08070 Barcelona, Spain
                [8 ]ISNI 0000 0001 2181 8870, GRID grid.5170.3, Center for Nanostructured Graphene (CNG), DTU Nanotech, , Technical University of Denmark, ; DK-2800 Kongens Lyngby, Denmark
                [9 ]ISNI 0000 0001 0930 2361, GRID grid.4514.4, MAX IV Laboratory and Lund University, ; 221 00 Lund, Sweden
                Author information
                http://orcid.org/0000-0003-4566-628X
                Article
                6940
                10.1038/s41467-018-06940-5
                6200825
                30356162
                729ae7ce-98b7-4a47-95b0-329d66680736
                © The Author(s) 2018

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 9 June 2018
                : 5 October 2018
                Funding
                Funded by: FundRef https://doi.org/10.13039/501100001659, Deutsche Forschungsgemeinschaft (German Research Foundation);
                Award ID: Te38613-1
                Award Recipient :
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