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      Nanofluid to Nanocomposite Film: Chitosan and Cellulose-Based Edible Packaging

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          Abstract

          Chitosan (CH)-based materials are compatible to form biocomposite film for food packaging applications. In order to enhance water resistance and mechanical properties, cellulose can be introduced to the chitosan-based film. In this work, we evaluate the morphology and water resistance of films prepared from chitosan and cellulose in their nanoscale form and study the phenomena underlying the film formation. Nanofluid properties are shown to be dependent on the particle form and drive the morphology of the prepared film. Film thickness and water resistance (in vapor or liquid phase) are clearly enhanced by the adjunction of nanocrystalline cellulose.

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          Review of recent research into cellulosic whiskers, their properties and their application in nanocomposite field.

          There are numerous examples where animals or plants synthesize extracellular high-performance skeletal biocomposites consisting of a matrix reinforced by fibrous biopolymers. Cellulose, the world's most abundant natural, renewable, biodegradable polymer, is a classical example of these reinforcing elements, which occur as whisker-like microfibrils that are biosynthesized and deposited in a continuous fashion. In many cases, this mode of biogenesis leads to crystalline microfibrils that are almost defect-free, with the consequence of axial physical properties approaching those of perfect crystals. This quite "primitive" polymer can be used to create high performance nanocomposites presenting outstanding properties. This reinforcing capability results from the intrinsic chemical nature of cellulose and from its hierarchical structure. Aqueous suspensions of cellulose crystallites can be prepared by acid hydrolysis of cellulose. The object of this treatment is to dissolve away regions of low lateral order so that the water-insoluble, highly crystalline residue may be converted into a stable suspension by subsequent vigorous mechanical shearing action. During the past decade, many works have been devoted to mimic biocomposites by blending cellulose whiskers from different sources with polymer matrixes.
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            Perspectives for chitosan based antimicrobial films in food applications

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              Current progress on bio-based polymers and their future trends

              This article reviews the recent trends, developments, and future applications of bio-based polymers produced from renewable resources. Bio-based polymers are attracting increased attention due to environmental concerns and the realization that global petroleum resources are finite. Bio-based polymers not only replace existing polymers in a number of applications but also provide new combinations of properties for new applications. A range of bio-based polymers are presented in this review, focusing on general methods of production, properties, and commercial applications. The review examines the technological and future challenges discussed in bringing these materials to a wide range of applications, together with potential solutions, as well as discusses the major industry players who are bringing these materials to the market. Electronic supplementary material The online version of this article (doi:10.1186/2194-0517-2-8) contains supplementary material, which is available to authorized users.
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                Author and article information

                Journal
                Nanomaterials (Basel)
                Nanomaterials (Basel)
                nanomaterials
                Nanomaterials
                MDPI
                2079-4991
                02 April 2020
                April 2020
                : 10
                : 4
                : 660
                Affiliations
                [1 ]Chemical Engineering Department, University of Sultan Ageng Tirtayasa, Jl Jendral Sudirman km 3, Cilegon 42435, Banten, Indonesia; mekro-permana.pinem@ 123456utc.fr
                [2 ]Integrated Transformations of Renewable Matter Laboratory (EA TIMR 4297 UTC-ESCOM), Sorbonne Universités, Université de Technologie de Compiègne, rue du Dr Schweitzer, 60200 Compiègne, France; daniele.clausse@ 123456utc.fr (D.C.); khashayar.saleh@ 123456utc.fr (K.S.)
                [3 ]Service d’Analyse Physico-Chimique (SAPC), Sorbonne Universités, Université de Technologie de Compiègne, rue du Dr Schweitzer, 60200 Compiègne, France; frederic.nadaud@ 123456utc.fr
                Author notes
                [* ]Correspondence: endarto.wardhono@ 123456untirta.ac.id (E.Y.W.); erwann.guenin@ 123456utc.fr (E.G.); Tel.: +62-254-395-502 (E.Y.W.); +33-344-234-584 (E.G.)
                Author information
                https://orcid.org/0000-0002-7925-1632
                https://orcid.org/0000-0002-7125-9074
                Article
                nanomaterials-10-00660
                10.3390/nano10040660
                7221946
                32252287
                72c29e6f-c7f0-4c9d-a3ac-290a3904b4f8
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 14 February 2020
                : 20 March 2020
                Categories
                Article

                chitosan,cellulose,nanofluid,nanocomposite film
                chitosan, cellulose, nanofluid, nanocomposite film

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