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      Group 13 decamethylmetallocenium cations

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          WinGXsuite for small-molecule single-crystal crystallography

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            Decamethyldizincocene, a stable compound of Zn(I) with a Zn-Zn bond.

            Unlike mercury, which has an extensive +1 oxidation state chemistry, zinc usually adopts the +2 oxidation state. Decamethyldizincocene, Zn2(eta5-C5Me5)2, an organometallic compound of Zn(I) formally derived from the dimetallic [Zn-Zn]2+ unit, has been isolated from the low-temperature (-10 degrees C) reaction of Zn(C5Me5)2 and Zn(C2H5)2 in diethyl ether. X-ray studies show that it contains two eclipsed Zn(eta5-C5Me5) fragments with a Zn-Zn distance (+/- standard deviation) of 2.305(+/-3) angstroms, indicative of a metal-metal bonding interaction.
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              Perfluorophenyl derivatives of the elements

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                Author and article information

                Journal
                ICHBD9
                Dalton Trans.
                Dalton Trans.
                Royal Society of Chemistry (RSC)
                1477-9226
                1477-9234
                2008
                2008
                :
                : 9
                : 1161-1176
                Article
                10.1039/B716220K
                © 2008
                Product
                Self URI (article page): http://xlink.rsc.org/?DOI=B716220K

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