The degree of intercalation of the polyvinyl alcohol-starch blend with the layered silicate is increased if the silicates is untreated or intercalated with ammonium ions that contain small radicals. If untreated silicate like NaMMT is used, it is possible to obtain exfoliated-intercalated nanocomposites. The materials based on PVOH, starch, and Nanocor I 28, Nanocor I 33, or Cloisite 15 A can be intercalated nanocomposites. If the blend of PVOH and starch is reinforced with Cloisite 93 A, microcomposites can result. The study will continue with the analysis of the new morphologies considering the transmission electron microscopy (TEM).