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      A chronology of global air quality

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          Abstract

          Air pollution has been recognized as a threat to human health since the time of Hippocrates, ca 400 BC. Successive written accounts of air pollution occur in different countries through the following two millennia until measurements, from the eighteenth century onwards, show the growing scale of poor air quality in urban centres and close to industry, and the chemical characteristics of the gases and particulate matter. The industrial revolution accelerated both the magnitude of emissions of the primary pollutants and the geographical spread of contributing countries as highly polluted cities became the defining issue, culminating with the great smog of London in 1952. Europe and North America dominated emissions and suffered the majority of adverse effects until the latter decades of the twentieth century, by which time the transboundary issues of acid rain, forest decline and ground-level ozone became the main environmental and political air quality issues. As controls on emissions of sulfur and nitrogen oxides (SO 2 and NO x ) began to take effect in Europe and North America, emissions in East and South Asia grew strongly and dominated global emissions by the early years of the twenty-first century. The effects of air quality on human health had also returned to the top of the priorities by 2000 as new epidemiological evidence emerged. By this time, extensive networks of surface measurements and satellite remote sensing provided global measurements of both primary and secondary pollutants. Global emissions of SO 2 and NO x peaked, respectively, in ca 1990 and 2018 and have since declined to 2020 as a result of widespread emission controls. By contrast, with a lack of actions to abate ammonia, global emissions have continued to grow.

          This article is part of a discussion meeting issue ‘Air quality, past present and future’.

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          Most cited references81

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          Historical (1850–2000) gridded anthropogenic and biomass burning emissions of reactive gases and aerosols: methodology and application

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            Environmental Quality and Development: Is There a Kuznets Curve for Air Pollution Emissions?

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              The global nitrogen cycle in the twenty-first century.

              Global nitrogen fixation contributes 413 Tg of reactive nitrogen (Nr) to terrestrial and marine ecosystems annually of which anthropogenic activities are responsible for half, 210 Tg N. The majority of the transformations of anthropogenic Nr are on land (240 Tg N yr(-1)) within soils and vegetation where reduced Nr contributes most of the input through the use of fertilizer nitrogen in agriculture. Leakages from the use of fertilizer Nr contribute to nitrate (NO3(-)) in drainage waters from agricultural land and emissions of trace Nr compounds to the atmosphere. Emissions, mainly of ammonia (NH3) from land together with combustion related emissions of nitrogen oxides (NOx), contribute 100 Tg N yr(-1) to the atmosphere, which are transported between countries and processed within the atmosphere, generating secondary pollutants, including ozone and other photochemical oxidants and aerosols, especially ammonium nitrate (NH4NO3) and ammonium sulfate (NH4)2SO4. Leaching and riverine transport of NO3 contribute 40-70 Tg N yr(-1) to coastal waters and the open ocean, which together with the 30 Tg input to oceans from atmospheric deposition combine with marine biological nitrogen fixation (140 Tg N yr(-1)) to double the ocean processing of Nr. Some of the marine Nr is buried in sediments, the remainder being denitrified back to the atmosphere as N2 or N2O. The marine processing is of a similar magnitude to that in terrestrial soils and vegetation, but has a larger fraction of natural origin. The lifetime of Nr in the atmosphere, with the exception of N2O, is only a few weeks, while in terrestrial ecosystems, with the exception of peatlands (where it can be 10(2)-10(3) years), the lifetime is a few decades. In the ocean, the lifetime of Nr is less well known but seems to be longer than in terrestrial ecosystems and may represent an important long-term source of N2O that will respond very slowly to control measures on the sources of Nr from which it is produced.
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                Author and article information

                Journal
                Philos Trans A Math Phys Eng Sci
                Philos Trans A Math Phys Eng Sci
                RSTA
                roypta
                Philosophical transactions. Series A, Mathematical, physical, and engineering sciences
                The Royal Society Publishing
                1364-503X
                1471-2962
                30 October 2020
                28 September 2020
                28 September 2020
                : 378
                : 2183 , Discussion meeting issue ‘Air quality, past present and future’ organised and edited by David Fowler, John Pyle, Mark Sutton and Martin Williams
                : 20190314
                Affiliations
                [1 ]Centre for Ecology and Hydrology , Penicuik, UK
                [2 ]School of Energy and Environment, City University of Hong Kong , Kowloon, Hong Kong
                [3 ]Faculty of Physics and Electrical Engineering, University of Bremen , Bremen, Germany
                [4 ]School of Chemistry, The University of Edinburgh , Edinburgh, UK
                [5 ]IVL Swedish Environmental Research Institute , Stockholm, Sweden
                [6 ]School of GeoSciences, University of Edinburgh , Edinburgh, UK
                [7 ]The Boundary, Goodley Stock Road Crockham Hill , Kent, UK
                [8 ]Environmental Science and Engineering, China Agricultural University , Beijing, People's Republic of China
                [9 ]Nanjing University of Information Science and Technology , Nanjing, Jiangsu, People's Republic of China
                [10 ]Imperial College London , London, UK
                [11 ]International Institute for Applied Systems Analysis (IIASA) , Laxenburg, Austria
                [12 ]Oregon State University , Corvallis, OR, USA
                Author notes

                One contribution of 17 to a discussion meeting issue ‘ Air quality, past present and future’.

                Author information
                http://orcid.org/0000-0002-2999-2627
                http://orcid.org/0000-0002-1765-6298
                http://orcid.org/0000-0002-8367-5833
                Article
                rsta20190314
                10.1098/rsta.2019.0314
                7536029
                32981430
                788735bc-7d2f-44de-9e01-4d9dd8e3228f
                © 2020 The Authors.

                Published by the Royal Society under the terms of the Creative Commons Attribution License http://creativecommons.org/licenses/by/4.0/, which permits unrestricted use, provided the original author and source are credited.

                History
                : 22 June 2020
                Categories
                1002
                11
                67
                1005
                19
                Articles
                Review Article
                Custom metadata
                October 30, 2020

                acid rain,air quality,ozone,eutrophication
                acid rain, air quality, ozone, eutrophication

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