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      Aeolian abrasion of rocks as a mechanism to produce methane in the Martian atmosphere

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          Abstract

          Seasonal changes in methane background levels and methane spikes have been detected in situ a metre above the Martian surface, and larger methane plumes detected via ground-based remote sensing, however their origin have not yet been adequately explained. Proposed methane sources include the UV irradiation of meteoritic-derived organic matter, hydrothermal reactions with olivine, organic breakdown via meteoroid impact, release from gas hydrates, biological production, or the release of methane from fluid inclusions in basalt during aeolian erosion. Here we quantify for the first time the potential importance of aeolian abrasion as a mechanism for releasing trapped methane from within rocks, by coupling estimates of present day surface wind abrasion with the methane contents of a variety of Martian meteorites, analogue terrestrial basalts and analogue terrestrial sedimentary rocks. We demonstrate that the abrasion of basalt under present day Martian rates of aeolian erosion is highly unlikely to produce detectable changes in methane concentrations in the atmosphere. We further show that, although there is a greater potential for methane production from the aeolian abrasion of certain sedimentary rocks, to produce the magnitude of methane concentrations analysed by the Curiosity rover they would have to contain methane in similar concentrations as economic reserved of biogenic/thermogenic deposits on Earth. Therefore we suggest that aeolian abrasion is an unlikely origin of the methane detected in the Martian atmosphere, and that other methane sources are required.

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          Most cited references39

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          Detection of methane in the atmosphere of Mars.

          We report a detection of methane in the martian atmosphere by the Planetary Fourier Spectrometer onboard the Mars Express spacecraft. The global average methane mixing ratio is found to be 10 +/- 5 parts per billion by volume (ppbv). However, the mixing ratio varies between 0 and 30 ppbv over the planet. The source of methane could be either biogenic or nonbiogenic, including past or present subsurface microorganisms, hydrothermal activity, or cometary impacts.
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            Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane

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              Strong release of methane on Mars in northern summer 2003.

              Living systems produce more than 90% of Earth's atmospheric methane; the balance is of geochemical origin. On Mars, methane could be a signature of either origin. Using high-dispersion infrared spectrometers at three ground-based telescopes, we measured methane and water vapor simultaneously on Mars over several longitude intervals in northern early and late summer in 2003 and near the vernal equinox in 2006. When present, methane occurred in extended plumes, and the maxima of latitudinal profiles imply that the methane was released from discrete regions. In northern midsummer, the principal plume contained approximately 19,000 metric tons of methane, and the estimated source strength (>/=0.6 kilogram per second) was comparable to that of the massive hydrocarbon seep at Coal Oil Point in Santa Barbara, California.
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                Author and article information

                Contributors
                jon.telling@newcastle.ac.uk
                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group UK (London )
                2045-2322
                3 June 2019
                3 June 2019
                2019
                : 9
                : 8229
                Affiliations
                [1 ]ISNI 0000 0001 0462 7212, GRID grid.1006.7, School of Natural and Environmental Sciences, , Newcastle University, ; Newcastle, NE1 7RU UK
                [2 ]ISNI 0000 0004 1936 7291, GRID grid.7107.1, School of Geosciences, , University of Aberdeen, ; Aberdeen, AB24 3FX UK
                [3 ]ISNI 0000 0001 2168 186X, GRID grid.134563.6, Lunar and Planetary Laboratory, , University of Arizona, ; Arizona, AZ 85721-0092 USA
                [4 ]ISNI 0000000096069301, GRID grid.10837.3d, School of Physical Sciences, , Open University, ; Milton Keynes, MK7 6AA UK
                [5 ]ISNI 0000 0004 1936 8884, GRID grid.39381.30, Department of Earth Sciences, , University of Western Ontario, ; Ontario, ON N6A 3K7 Canada
                [6 ]ISNI 0000 0004 1936 7988, GRID grid.4305.2, School of Physics and Astronomy, , University of Edinburgh, ; Edinburgh, EH9 3FD UK
                [7 ]ISNI 0000 0004 1936 7603, GRID grid.5337.2, School of Geographical Sciences, , University of Bristol, ; Bristol, BS8 1SS UK
                [8 ]ISNI 0000 0000 8700 0572, GRID grid.8250.f, Department of Earth Sciences, , Durham University, ; Durham, DH1 3LE UK
                Author information
                http://orcid.org/0000-0002-8223-3566
                http://orcid.org/0000-0003-3662-0503
                Article
                44616
                10.1038/s41598-019-44616-2
                6546745
                31160623
                7b97f968-8fd1-4344-bacc-f29dfd2718ec
                © The Author(s) 2019

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 24 October 2018
                : 16 May 2019
                Funding
                Funded by: FundRef https://doi.org/10.13039/100011690, UK Space Agency (United Kingdom Space Agency);
                Award ID: ST/R001421/1
                Award Recipient :
                Funded by: UK Space Agency Grant ST/R001421/1
                Categories
                Article
                Custom metadata
                © The Author(s) 2019

                Uncategorized
                atmospheric chemistry,geochemistry
                Uncategorized
                atmospheric chemistry, geochemistry

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