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      Anwendungen der Katalyse mit N-heterocyclischen Carbenen in Totalsynthesen

      , , ,
      Angewandte Chemie
      Wiley-Blackwell

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          Organocatalysis by N-heterocyclic carbenes.

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            N-Heterocyclic Carbenes as Organocatalysts

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              Organocatalytic umpolung: N-heterocyclic carbenes and beyond.

              The umpolung strategy encompasses all the methods that make organic molecules react in an inverse manner compared to their innate polarity-driven reactivity. This concept entered the field of organocatalysis when it was recognized that N-heterocyclic carbenes (NHCs) can provide catalytic access to acyl anion equivalents. Since then, tremendous efforts have followed to develop a broad variety of NHC-catalyzed reactions. In addition to this, more recent research developments have shown that other families of organocatalysts are also able to mediate transformations in which inversion of polarity is involved. This tutorial review aims at offering a didactic overview of organocatalytic umpolung and should serve as an inspiration for further progress in this field.
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                Author and article information

                Journal
                Angewandte Chemie
                Angew. Chem.
                Wiley-Blackwell
                00448249
                November 19 2012
                November 19 2012
                : 124
                : 47
                : 11854-11866
                Article
                10.1002/ange.201203704
                7d3c4340-1538-4769-aae7-b0f1bf858233
                © 2012

                http://doi.wiley.com/10.1002/tdm_license_1.1

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