High performance hybrid solar cells sensitized by organolead halide perovskites

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Dye-sensitized solar cells.

Anders Hagfeldt, Gerrit Boschloo, Licheng Sun … (2011)

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Hybrid nanorod-polymer solar cells.

Wendy U. Huynh, Janke J. Dittmer, A Alivisatos (2002)

We demonstrate that semiconductor nanorods can be used to fabricate readily processed and efficient hybrid solar cells together with polymers. By controlling nanorod length, we can change the distance on which electrons are transported directly through the thin film device. Tuning the band gap by altering the nanorod radius enabled us to optimize the overlap between the absorption spectrum of the cell and the solar emission spectrum. A photovoltaic device consisting of 7-nanometer by 60-nanometer CdSe nanorods and the conjugated polymer poly-3(hexylthiophene) was assembled from solution with an external quantum efficiency of over 54% and a monochromatic power conversion efficiency of 6.9% under 0.1 milliwatt per square centimeter illumination at 515 nanometers. Under Air Mass (A.M.) 1.5 Global solar conditions, we obtained a power conversion efficiency of 1.7%.

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Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors

Kagan, Mitzi, Dimitrakopoulos (1999)

Organic-inorganic hybrid materials promise both the superior carrier mobility of inorganic semiconductors and the processability of organic materials. A thin-film field-effect transistor having an organic-inorganic hybrid material as the semiconducting channel was demonstrated. Hybrids based on the perovskite structure crystallize from solution to form oriented molecular-scale composites of alternating organic and inorganic sheets. Spin-coated thin films of the semiconducting perovskite (C(6)H(5)C(2)H(4)NH(3))(2)SnI(4) form the conducting channel, with field-effect mobilities of 0.6 square centimeters per volt-second and current modulation greater than 10(4). Molecular engineering of the organic and inorganic components of the hybrids is expected to further improve device performance for low-cost thin-film transistors.

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Journal

Journal ID (publisher-id): EESNBY

Title: Energy & Environmental Science

Abbreviated Title: Energy Environ. Sci.

Publisher: Royal Society of Chemistry (RSC)

ISSN (Print): 1754-5692

ISSN (Electronic): 1754-5706

Publication date Created: 2013

Publication date (Print): 2013

Volume: 6

Issue: 5

Page: 1480

Article

DOI: 10.1039/c3ee40343b

SO-VID: 7da67aa7-f7a6-4452-b255-11d4060dcb36

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High performance hybrid solar cells sensitized by organolead halide perovskites

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Abstract

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Silicon thin film solar cells

Most cited references 37

Dye-sensitized solar cells.

Hybrid nanorod-polymer solar cells.

Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors

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Cited by 210

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