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      Magnetothermal Convection of Water with the Presence or Absence of a Magnetic Force Acting on the Susceptibility Gradient

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          Abstract

          Heat transfer of magnetothermal convection with the presence or absence of the magnetic force acting on the susceptibility gradient ( f sc) was examined by three-dimensional numerical computations. Thermal convection of water enclosed in a shallow cylindrical vessel (diameter over vessel height = 6.0) with the Rayleigh-Benard model was adopted as the model, under the conditions of Prandtl number 6.0 and Ra number 7000, respectively. The momentum equations of convection were nondimensionalized, which involved the term of f sc and the term of magnetic force acting on the magnetic field gradient ( f b). All the computations resulted in axisymmetric steady rolls. The values of the averaged Nu, the averaged velocity components U, V, and W, and the isothermal distributions and flow patterns were almost completely the same, regardless of the presence or absence of the term of f sc. As a result, we found that the effect of f sc was extremely small, although much previous research emphasized the effect with paramagnetic solutions under an unsteady state. The magnitude of f sc depends not only on magnetic conditions (magnitudes of magnetic susceptibility and magnetic flux density), but also on the thermal properties of the solution (thermal conductivity, thermal diffusivity, and viscosity). Therefore the effect of f b becomes dominant on the magnetothermal convection. Active control over the density gradient with temperature will be required to advance heat transfer with the effect of f sc.

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          Magnetic levitation: Floating gold in cryogenic oxygen.

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            Magnet used for protein crystallization: novel attempts to improve the crystal quality.

            The accuracy of the structures of biological macromolecules determined by X-ray crystallography is of fundamental importance, both for the understanding of life processes and for medical applications. The resolution of the structure is thus critical, and is largely determined by the quality of single crystals. Here we report the results of applying a magnetic field and a magnetization force during growth of the snake muscle fructose-1,6-bisphosphatase and human estrogenic 17beta-hydroxysteroid dehydrogenase crystals. For both enzyme proteins, the quality of the crystals improved with repeated assay, and their data sets were collected at significantly higher resolutions. These results coincide with a mechanism involving the reduction of convection, due to both the hydrodynamics within a magnet and the partially reduced gravity induced by a magnetization force. The density difference between the crystal and solution becomes less significant, and the sedimentation speed of the crystals is also reduced in the presence of the magnetization force.
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              Demonstration of the elusive concentration-gradient paramagnetic force.

              Using classical electrochemistry, it is demonstrated that the concentration-gradient paramagnetic force, FnablaC, is a body force proportional to |B|2 acting parallel to the concentration gradient of electrogenerated radicals. FnablaC can balance gravity, holding volumes of solution wherein mass transfer continues to take place by diffusion. In contrast to usual levitation forces, FnablaC does not depend on field gradients and may be present even in homogeneous magnetic fields. Understanding the properties of FnablaC is relevant to magnetic confinement and levitation and is speculated even to propulsion with objects having permanent susceptibility gradients.
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                Author and article information

                Contributors
                Role: Editor
                Journal
                PLoS One
                PLoS ONE
                plos
                plosone
                PLoS ONE
                Public Library of Science (San Francisco, CA USA )
                1932-6203
                8 September 2016
                2016
                : 11
                : 9
                : e0160090
                Affiliations
                [001]Laboratory of Molecular Chemistry, Faculty of Pharmacy, Osaka Ohtani University, 3-11-1, Nishikiori-kita, Tondabayashi City, Osaka Pref. 584-8540, Japan
                University of Glasgow, UNITED KINGDOM
                Author notes

                Competing Interests: The authors have declared that no competing interests exist.

                • Conceived and designed the experiments: SM.

                • Performed the experiments: SM.

                • Analyzed the data: SM.

                • Contributed reagents/materials/analysis tools: SM.

                • Wrote the paper: SM.

                Article
                PONE-D-15-52348
                10.1371/journal.pone.0160090
                5015909
                27606823
                7e64dfce-f3ce-40e8-9f4f-f4f0d8a2dc2c
                © 2016 Syou Maki

                This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

                History
                : 2 December 2015
                : 13 July 2016
                Page count
                Figures: 6, Tables: 6, Pages: 26
                Funding
                Funded by: JSPS KAKENHI
                Award ID: Grant number 15K04669
                Award Recipient :
                The author, S. Maki, received the following specific funding for this work. JSPS (Japan Society for the Promotion of Science) KAKENHI (Grant-in-Aid for Scientific Research) (C) (Grant number 15K04669).
                Categories
                Research Article
                Physical Sciences
                Physics
                Classical Mechanics
                Convection
                Physical Sciences
                Materials Science
                Materials by Attribute
                Magnets
                Physical Sciences
                Physics
                Condensed Matter Physics
                Magnetism
                Magnetic Fields
                Physical Sciences
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                Gravitation
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                Classical Mechanics
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                Viscosity
                Physical Sciences
                Materials Science
                Materials Physics
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                Physical Sciences
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                Materials Physics
                Viscosity
                Physical Sciences
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                Mixtures
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