Iodine-Catalyzed Regioselective Sulfenylation of Indoles with Sulfonyl Hydrazides

Yang, Fu-Lai; Tian, Shi-Kai

doi:10.1002/anie.201301437

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Iodine-Catalyzed Regioselective Sulfenylation of Indoles with Sulfonyl Hydrazides

Author(s): Fu-Lai Yang , Shi-Kai Tian

Publication date Created: April 26 2013

Publication date (Print): April 26 2013

Journal: Angewandte Chemie International Edition

Publisher: Wiley-Blackwell

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Tosylhydrazones: New Uses for Classic Reagents in Palladium-Catalyzed Cross-Coupling and Metal-Free Reactions

José Barluenga, Carlos Valdes (2011)

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N-Tosylhydrazones: versatile reagents for metal-catalyzed and metal-free cross-coupling reactions

Hongbin Zhang, Zhihui Shao (2012)

Transition metal-catalyzed cross-coupling reactions have been established as one of the most powerful tools for the construction of C-C and C-X bonds. In this context, the development of novel metal-catalyzed cross-coupling processes that do not require stoichiometric organometallic reagents is particularly attractive. Recently, N-tosylhydrazones have emerged as a new type of versatile coupling partners for transition metal-catalyzed cross-coupling reactions as well as metal-free cross-coupling reactions, and have attracted increasing attention. This tutorial review summarizes recent important developments in this area with N-tosylhydrazones as versatile coupling partners.