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      Biosurfactants as an alternative eco-friendly solution for water-in-diesel emulsions-A review paper

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          Abstract

          Diesel engines are used extensively in heavy-duty transportation due to their high thermal efficiency and energy density, but they also contribute to environmental pollution. Water-in-diesel emulsions have emerged as an alternative method for decreasing NOx and emissions, but there are still obstacles to assuring engine performance and stability. Surfactants are used to stabilise the emulsion by decreasing the interfacial tension between the fuel and water. Studies on water-in-diesel emulsions published literature suggest that chemical surfactants have been used in the production of emulsified fuels. In addition, research have shown that biosurfactants are less harmful to the environment than chemical surfactants. However, only limited study has been conducted on the use of biosurfactants in emulsified fuel. Consequently, it is important to investigate the possible use of biosurfactants in applications using emulsified fuels. This research studies the categorization of surfactants and biosurfactants and emulsion methods for the development of emulsified fuel. This research also aids in the selection of the most suitable surfactant and biosurfactant for applications, particularly in the context of water-in-diesel emulsions and diesel-in-water emulsions, with the goal of developing an environmentally friendly, stable emulsified fuel that can reduce the emission effect and protect the environment.

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          Most cited references103

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          Nanoemulsions: formation, properties and applications.

          Nanoemulsions are kinetically stable liquid-in-liquid dispersions with droplet sizes on the order of 100 nm. Their small size leads to useful properties such as high surface area per unit volume, robust stability, optically transparent appearance, and tunable rheology. Nanoemulsions are finding application in diverse areas such as drug delivery, food, cosmetics, pharmaceuticals, and material synthesis. Additionally, they serve as model systems to understand nanoscale colloidal dispersions. High and low energy methods are used to prepare nanoemulsions, including high pressure homogenization, ultrasonication, phase inversion temperature and emulsion inversion point, as well as recently developed approaches such as bubble bursting method. In this review article, we summarize the major methods to prepare nanoemulsions, theories to predict droplet size, physical conditions and chemical additives which affect droplet stability, and recent applications.
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            Environmental applications for biosurfactants.

            Biosurfactants are surfactants that are produced extracellularly or as part of the cell membrane by bacteria, yeasts and fungi. Examples include Pseudomonas aeruginosa which produces rhamnolipids, Candida (formerly Torulopsis) bombicola, one of the few yeasts to produce biosurfactants, which produces high yields of sophorolipids from vegetable oils and sugars and Bacillus subtilis which produces a lipopeptide called surfactin. This review includes environmental applications of these biosurfactants for soil and water treatment. Biosurfactant applications in the environmental industries are promising due to their biodegradability, low toxicity and effectiveness in enhancing biodegradation and solubilization of low solubility compounds. However, more information is needed to be able to predict and model their behaviour. Full scale tests will be required. The role of biosurfactants in natural attenuation processes has not been determined. Very little information is available concerning the influence of soil components on the remediation process with biosurfactants. As most of the research until now has been performed with rhamnolipids, other biosurfactants need to be investigated as they may have more promising properties.
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              The use of ultrasonics for nanoemulsion preparation

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                Author and article information

                Contributors
                Journal
                Heliyon
                Heliyon
                Heliyon
                Elsevier
                2405-8440
                06 September 2024
                15 September 2024
                06 September 2024
                : 10
                : 17
                : e37485
                Affiliations
                [a ]Center of Sustainable Resources for Intelligent and Efficient Mobility (CSRIEM), Mechanical Engineering Department, Universiti Teknologi PETRONAS, Seri Iskandar, Perak, 32610,Malaysia
                [b ]Mechanical Engineering Department, MUET SZAB Campus Khairpur Mir's, 66020, Pakistan
                [c ]Engineering Department, College of Engineering, Najran University, Najran, 61441, Saudi Arabia
                Author notes
                [* ]Corresponding author. asghar_21002752@ 123456utp.edu.my
                [** ]Corresponding author. mhadi.abaker@ 123456utp.edu.my
                Article
                S2405-8440(24)13516-5 e37485
                10.1016/j.heliyon.2024.e37485
                11407060
                39290264
                7fdf78c7-394c-4e12-936c-9f2dc8785f6c
                © 2024 The Author(s)

                This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).

                History
                : 20 October 2023
                : 3 September 2024
                : 4 September 2024
                Categories
                Review Article

                wide,emulsion,surfactant,biosurfactant,emulsified fuel properties,micro-explosion

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