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      Incorporation of imidazole within the metal-organic framework UiO-67 for enhanced anhydrous proton conductivity.

      1 , ,

      Dalton transactions (Cambridge, England : 2003)

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          Abstract

          Imidazole was introduced into the channels of the metal-organic framework UiO-67 using an evaporation method. The imidazole@UiO-67 composite presents a high proton conductivity of 1.44 × 10(-3) S cm(-1) at 120 °C under anhydrous conditions. With a low activation energy at high temperatures (0.36 eV), the hybrid material can be regarded as a superionic conductor.

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          Author and article information

          Journal
          Dalton Trans
          Dalton transactions (Cambridge, England : 2003)
          1477-9234
          1477-9226
          Aug 7 2015
          : 44
          : 29
          Affiliations
          [1 ] College of Science, Guizhou University, Guiyang 550025, China. sci.yiliu@gzu.edu.cn.
          Article
          10.1039/c5dt01667c
          26126755

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