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      The Mechanical Properties of Nanowires

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          Abstract

          Applications of nanowires into future generation nanodevices require a complete understanding of the mechanical properties of the nanowires. A great research effort has been made in the past two decades to understand the deformation physics and mechanical behaviors of nanowires, and to interpret the discrepancies between experimental measurements and theoretical predictions. This review focused on the characterization and understanding of the mechanical properties of nanowires, including elasticity, plasticity, anelasticity and strength. As the results from the previous literature in this area appear inconsistent, a critical evaluation of the characterization techniques and methodologies were presented. In particular, the size effects of nanowires on the mechanical properties and their deformation mechanisms were discussed.

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          Most cited references279

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          Electrostatic deflections and electromechanical resonances of carbon nanotubes

          Static and dynamic mechanical deflections were electrically induced in cantilevered, multiwalled carbon nanotubes in a transmission electron microscope. The nanotubes were resonantly excited at the fundamental frequency and higher harmonics as revealed by their deflected contours, which correspond closely to those determined for cantilevered elastic beams. The elastic bending modulus as a function of diameter was found to decrease sharply (from about 1 to 0.1 terapascals) with increasing diameter (from 8 to 40 nanometers), which indicates a crossover from a uniform elastic mode to an elastic mode that involves wavelike distortions in the nanotube. The quality factors of the resonances are on the order of 500. The methods developed here have been applied to a nanobalance for nanoscopic particles and also to a Kelvin probe based on nanotubes.
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            Mechanical annealing and source-limited deformation in submicrometre-diameter Ni crystals.

            The fundamental processes that govern plasticity and determine strength in crystalline materials at small length scales have been studied for over fifty years. Recent studies of single-crystal metallic pillars with diameters of a few tens of micrometres or less have clearly demonstrated that the strengths of these pillars increase as their diameters decrease, leading to attempts to augment existing ideas about pronounced size effects with new models and simulations. Through in situ nanocompression experiments inside a transmission electron microscope we can directly observe the deformation of these pillar structures and correlate the measured stress values with discrete plastic events. Our experiments show that submicrometre nickel crystals microfabricated into pillar structures contain a high density of initial defects after processing but can be made dislocation free by applying purely mechanical stress. This phenomenon, termed 'mechanical annealing', leads to clear evidence of source-limited deformation where atypical hardening occurs through the progressive activation and exhaustion of dislocation sources.
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              Size dependence of Young's modulus in ZnO nanowires.

              We report a size dependence of Young's modulus in [0001] oriented ZnO nanowires (NWs) with diameters ranging from 17 to 550 nm for the first time. The measured modulus for NWs with diameters smaller than about 120 nm is increasing dramatically with the decreasing diameters, and is significantly higher than that of the larger ones whose modulus tends to that of bulk ZnO. A core-shell composite NW model in terms of the surface stiffening effect correlated with significant bond length contractions occurred near the {1010} free surfaces (which extend several layers deep into the bulk and fade off slowly) is proposed to explore the origin of the size dependence, and present experimental result is well explained. Furthermore, it is possible to estimate the size-related elastic properties of GaN nanotubes and relative nanostructures by using this model.
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                Author and article information

                Contributors
                han.huang@uq.edu.au
                Journal
                Adv Sci (Weinh)
                Adv Sci (Weinh)
                10.1002/(ISSN)2198-3844
                ADVS
                Advanced Science
                John Wiley and Sons Inc. (Hoboken )
                2198-3844
                03 January 2017
                April 2017
                : 4
                : 4 ( doiID: 10.1002/advs.v4.4 )
                : 1600332
                Affiliations
                [ 1 ] School of Mechanical and Mining EngineeringThe University of Queensland Australia
                [ 2 ] Center for Advancing Materials Performance from the NanoscaleXi'an Jiaotong University China
                Author notes
                Article
                ADVS250
                10.1002/advs.201600332
                5396167
                28435775
                81f285d8-2ed7-4edf-8c26-d0084ac21bbe
                © 2017 The Authors. Published by WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

                This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

                History
                : 31 August 2016
                : 17 September 2016
                Page count
                Figures: 27, Tables: 1, Pages: 24, Words: 18998
                Funding
                Funded by: Australian Research Council
                Award ID: DP160103190
                Funded by: NSFC
                Award ID: 51231005
                Award ID: 51321003
                Categories
                Review
                Reviews
                Custom metadata
                2.0
                advs250
                April 2017
                Converter:WILEY_ML3GV2_TO_NLMPMC version:5.0.9 mode:remove_FC converted:19.04.2017

                characterization,mechanical properties,nanowires,size effect

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