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C–H nitrogenation and oxygenation by ruthenium catalysis

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      Palladium-catalyzed ligand-directed C-H functionalization reactions.

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        Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality.

        In the past decade, palladium-catalyzed C-H activation/C-C bond-forming reactions have emerged as promising new catalytic transformations; however, development in this field is still at an early stage compared to the state of the art in cross-coupling reactions using aryl and alkyl halides. This Review begins with a brief introduction of four extensively investigated modes of catalysis for forming C-C bonds from C-H bonds: Pd(II)/Pd(0), Pd(II)/Pd(IV), Pd(0)/Pd(II)/Pd(IV), and Pd(0)/Pd(II) catalysis. A more detailed discussion is then directed towards the recent development of palladium(II)-catalyzed coupling of C-H bonds with organometallic reagents through a Pd(II)/Pd(0) catalytic cycle. Despite the progress made to date, improving the versatility and practicality of this new reaction remains a tremendous challenge.
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          Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

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            Author and article information

            Journal
            CHCOFS
            Chem. Commun.
            Chem. Commun.
            Royal Society of Chemistry (RSC)
            1359-7345
            1364-548X
            2014
            2014
            : 50
            : 1
            : 29-39
            10.1039/C3CC47028H
            © 2014
            Product
            Self URI (article page): http://xlink.rsc.org/?DOI=C3CC47028H

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