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      Growth of γ-Fe2O3 nanosheet arrays on graphene for electromagnetic absorption applications

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          Abstract

          A new strategy was developed to grow γ-Fe 2O 3 nanosheet arrays on graphene sheets, showing excellent electromagnetic wave absorption properties with a lightweight characteristic.

          Abstract

          We developed a seed-assisted method to grow ultra-thin γ-Fe 2O 3 nanosheets with a paramagnetic behaviour on the surfaces of graphene sheets. Scanning electron microscopy and the transmission electron microscopy measurements showed that the length, height and thickness of the nanosheets were about 140, 120 and 5 nm, respectively. The measured electromagnetic parameters indicated that the three-dimensional (3D) graphene/γ-Fe 2O 3 nanosheet arrays exhibited a significantly enhanced electromagnetic wave absorption property compared to that of the graphene sheets and some magnetic nanomaterials. The minimal reflection loss was less than −15.2 dB for 3D graphene/γ-Fe 2O 3 nanosheet arrays with thicknesses of 2 mm, and it was up to −64.1 dB when the thickness was 4.92 mm. Good electromagnetic wave absorption properties of the 3D graphene/γ-Fe 2O 3 nanosheet arrays indicate that they are very promising for applications in the electromagnetic wave absorbing field.

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          Microwave Absorption Enhancement and Complex Permittivity and Permeability of Fe Encapsulated within Carbon Nanotubes

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            Raman microspectroscopy of some iron oxides and oxyhydroxides

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              Is Open Access

              Ni(OH)2 Nanoplates Grown on Graphene as Advanced Electrochemical Pseudocapacitor Materials

              Ni(OH)2 nanocrystals grown on graphene sheets with various degrees of oxidation are investigated as electrochemical pseudocapacitor materials for potential energy storage applications. Single-crystalline Ni(OH)2 hexagonal nanoplates directly grown on lightly-oxidized, electrically-conducting graphene sheets (GS) exhibit a high specific capacitance of ~1335F/g at a charge and discharge current density of 2.8A/g and ~953F/g at 45.7A/g with excellent cycling ability. The high specific capacitance and remarkable rate capability are promising for applications in supercapacitors with both high energy and power densities. Simple physical mixture of pre-synthesized Ni(OH)2 nanoplates and graphene sheets show lower specific capacitance, highlighting the importance of direct growth of nanomaterials on graphene to impart intimate interactions and efficient charge transport between the active nanomaterials and the conducting graphene network. Single-crystalline Ni(OH)2 nanoplates directly grown on graphene sheets also significantly outperform small Ni(OH)2 nanoparticles grown on heavily-oxidized, electrically-insulating graphite oxide (GO), suggesting that the electrochemical performance of these composites are dependent on the quality of graphene substrates and the morphology and crystallinity of the nanomaterials grown on top. These results suggest the importance of rational design and synthesis of graphene-based nanocomposite materials for high-performance energy applications.
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                Author and article information

                Journal
                RSCACL
                RSC Adv.
                RSC Adv.
                Royal Society of Chemistry (RSC)
                2046-2069
                2014
                2014
                : 4
                : 41
                : 21510-21516
                Affiliations
                [1 ]Key Laboratory Superlight Materials and Surface Technology
                [2 ]Ministry of Education
                [3 ]College of Materials Science and Chemical Engineering
                [4 ]Harbin Engineering University
                [5 ]Harbin, China
                [6 ]College of Science
                [7 ]Harbin 150001, China
                [8 ]Key Laboratory for Photonic and Electric Bandgap Materials
                [9 ]Harbin Normal University
                [10 ]Harbin, P.R. China
                Article
                10.1039/C4RA01082E
                84817f04-03e2-4a79-ba34-753128ecda35
                © 2014
                History

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