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Bicyclic Aziridinium Ions in Azaheterocyclic Chemistry - Preparation and Synthetic Application of 1-Azoniabicyclo[n.1.0]alkanes

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      Most cited references 60

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      Nucleophilic ring opening of aziridines

       X.Eric Hu (2004)
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        Synthesis and reactivity of C-heteroatom-substituted aziridines.

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          Regioselectivity in the ring opening of non-activated aziridines.

          In this critical review, the ring opening of non-activated 2-substituted aziridines via intermediate aziridinium salts will be dealt with. Emphasis will be put on the relationship between the observed regioselectivity and inherent structural features such as the nature of the C2 aziridine substituent and the nature of the electrophile and the nucleophile. This overview should allow chemists to gain insight into the factors governing the regioselectivity in aziridinium ring openings (81 references).
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            Author and article information

            Journal
            Advanced Synthesis & Catalysis
            Adv. Synth. Catal.
            Wiley
            16154150
            November 17 2016
            November 17 2016
            : 358
            : 22
            : 3485-3511
            10.1002/adsc.201600750
            © 2016

            http://doi.wiley.com/10.1002/tdm_license_1.1

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