Nowadays there is a widespread phenomenon of dairy residue, which causes a great deal of waste. To solve this problem, the copolymer of fluorinated acrylate resin was synthesized and the resisting fluid film was prepared. The proprieties of the fluorinated acrylate resin coatings were characterized by scanning electron microscope (SEM), measuring the contact angle of the droplet liquid on the surface of the coating, the influence of acidic environment, the adhesion to substrate material, and analyzing thermogravimetry (TG) and Gas Chromatography (GC). It was found that the fluorinated acrylate resin film is a kind of resisting fluid film with excellent property and it is safe, nontoxic and readily biodegradable. So it was said a very potential dairy packaging material.