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      Interrelationship of Pyrogenic Polycyclic Aromatic Hydrocarbon (PAH) Contamination in Different Environmental Media

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          Abstract

          Interrelationships between pyrogenic polycyclic aromatic hydrocarbons (PAHs) were assessed in air, soil, water, sediment, and tree leaves by using multi-media monitoring data. Concurrent concentration measurements were taken bimonthly for a year for the multi-media at urban and suburban sites. PAH level correlations between air and other media were observed at the urban site but were less clear at the suburban site. Considering a closer PAHs distribution/fate characteristics to soil than suspended solids, contamination in sediment seemed to be governed primarily by that in soil. The partitioning of PAHs in waters could be better accounted for by sorption onto black carbon and dissolved organic carbon.

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          Quantification of the Dilute Sedimentary Soot Phase:  Implications for PAH Speciation and Bioavailability

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            Partition equilibriums of nonionic organic compounds between soil organic matter and water.

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              Black carbon: the reverse of its dark side.

              The emission of black carbon is known to cause major environmental problems. Black carbon particles contribute to global warming, carry carcinogenic compounds and cause serious health risks. Here, we show another side of the coin. We review evidence that black carbon may strongly reduce the risk posed by organic contaminants in sediments and soils. Extremely efficient sorption to black carbon pulls highly toxic polycyclic aromatic hydrocarbons, polychlorinated biphenyls, dioxins, polybrominated diphenylethers and pesticides into sediments and soils. This increased sorption is general, but strongest for planar (most toxic) compounds at environmentally relevant, low aqueous concentrations. Black carbon generally comprises about 9% of total organic carbon in aquatic sediments (median value of 300 sediments), and then may reduce uptake in organisms by up to two orders of magnitude. This implies that current environmental risk assessment systems for these contaminants may be unnecessarily safe.
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                Author and article information

                Journal
                Sensors (Basel)
                Sensors (Basel, Switzerland)
                Molecular Diversity Preservation International (MDPI)
                1424-8220
                2009
                30 November 2009
                : 9
                : 12
                : 9582-9602
                Affiliations
                [1 ] School of Earth and Environmental Sciences (BK-21), Seoul National University, Kwanakgu Kwanakro 599, Seoul 151-742, South Korea; E-Mail: skkim89@ 123456gmail.com
                [2 ] Graduate School of Environmental Studies, Environmental Planning Institute, Seoul National University, Kwanakgu Kwanakro 599, Seoul 151-742, South Korea
                [3 ] Oil & POPs Research Group, Korea Ocean Research and Development Institute, 391 Jangmok-ri, Jangmok-myon, Geoje-shi 656-834, South Korea; E-Mails: wjshim@ 123456kordi.re.kr (W.J.S.); uhyim@ 123456kordi.re.kr (U.H.Y.)
                [4 ] Environmental Policy Division, Korea Environment Institute, Eunpyung ku, Bulkwang dong 613-2, Seoul 122-706, South Korea; E-Mail: shiny@ 123456kei.re.kr
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: leeds@ 123456snu.ac.kr ; Tel.: +82-2-880-8522; Fax: +82-2-871-8847.
                Article
                sensors-09-09582
                10.3390/s91209582
                3267189
                22303141
                8681369e-e75c-4ab8-9a86-5d88e0e08ef7
                © 2009 by the authors; licensee Molecular Diversity Preservation International, Basel, Switzerland.

                This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/3.0/).

                History
                : 30 October 2009
                : 16 November 2009
                : 17 November 2009
                Categories
                Article

                Biomedical engineering
                pahs,fugacity ratio,multi-media fate,black carbon,partitioning equilibrium
                Biomedical engineering
                pahs, fugacity ratio, multi-media fate, black carbon, partitioning equilibrium

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