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      [2+2] Photocycloaddition of 3-Alkenyloxy-2-cycloalkenones: Enantioselective Lewis Acid Catalysis and Ring Expansion

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      Angewandte Chemie International Edition

      Wiley-Blackwell

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          Donor-acceptor-substituted cyclopropane derivatives and their application in organic synthesis.

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            Photochemical reactions as key steps in organic synthesis.

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              Heterocycles from cyclopropanes: applications in natural product synthesis.

              The construction of heterocyclic compounds from activated cyclopropane derivatives offers an alternative strategy for the preparation of molecules that may be of interest from a structural or biological standpoint. Several newly developed methods provide access to densely functionalized heterocycles in a manner that can be considered useful for both diversity- and target-oriented synthetic approaches. This tutorial review focuses on the latter, describing recent developments and applications of cyclopropane ring-expansion reactions in natural product synthesis.
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                Author and article information

                Journal
                Angewandte Chemie International Edition
                Angew. Chem. Int. Ed.
                Wiley-Blackwell
                14337851
                November 17 2014
                November 17 2014
                : 53
                : 47
                : 12921-12924
                Article
                10.1002/anie.201407832
                © 2014

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