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      Nanophotonics-enabled solar membrane distillation for off-grid water purification

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          Abstract

          <p id="d2616390e473">Current desalination technologies provide solutions to the increasing water demands of the planet but require substantial electric energy, limiting their sustainable use where conventional power infrastructure may be unavailable. Here, we report a direct solar method for desalination that utilizes nanoparticle-assisted solar vaporization in a membrane distillation geometry. This scalable process is capable of providing sufficient clean water for family use in a compact footprint, potentially for off-grid desalination at remote locations. </p><p class="first" id="d2616390e476">With more than a billion people lacking accessible drinking water, there is a critical need to convert nonpotable sources such as seawater to water suitable for human use. However, energy requirements of desalination plants account for half their operating costs, so alternative, lower energy approaches are equally critical. Membrane distillation (MD) has shown potential due to its low operating temperature and pressure requirements, but the requirement of heating the input water makes it energy intensive. Here, we demonstrate nanophotonics-enabled solar membrane distillation (NESMD), where highly localized photothermal heating induced by solar illumination alone drives the distillation process, entirely eliminating the requirement of heating the input water. Unlike MD, NESMD can be scaled to larger systems and shows increased efficiencies with decreased input flow velocities. Along with its increased efficiency at higher ambient temperatures, these properties all point to NESMD as a promising solution for household- or community-scale desalination. </p>

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          Most cited references41

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          3D self-assembly of aluminium nanoparticles for plasmon-enhanced solar desalination

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            Membrane distillation: A comprehensive review

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              Solar vapor generation enabled by nanoparticles.

              Solar illumination of broadly absorbing metal or carbon nanoparticles dispersed in a liquid produces vapor without the requirement of heating the fluid volume. When particles are dispersed in water at ambient temperature, energy is directed primarily to vaporization of water into steam, with a much smaller fraction resulting in heating of the fluid. Sunlight-illuminated particles can also drive H(2)O-ethanol distillation, yielding fractions significantly richer in ethanol content than simple thermal distillation. These phenomena can also enable important compact solar applications such as sterilization of waste and surgical instruments in resource-poor locations.
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                Author and article information

                Journal
                Proceedings of the National Academy of Sciences
                Proc Natl Acad Sci USA
                Proceedings of the National Academy of Sciences
                0027-8424
                1091-6490
                July 03 2017
                July 03 2017
                : 114
                : 27
                : 6936-6941
                Article
                10.1073/pnas.1701835114
                5502612
                28630307
                8a47f4b7-fb8f-4b69-96bf-0e4ca8e50770
                © 2017

                http://www.pnas.org/site/misc/userlicense.xhtml

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