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      Impact of climate changes during the last 5 million years on groundwater in basement aquifers

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          Abstract

          Climate change is thought to have major effects on groundwater resources. There is however a limited knowledge of the impacts of past climate changes such as warm or glacial periods on groundwater although marine or glacial fluids may have circulated in basements during these periods. Geochemical investigations of groundwater at shallow depth (80–400 m) in the Armorican basement (western France) revealed three major phases of evolution: (1) Mio-Pliocene transgressions led to marine water introduction in the whole rock porosity through density and then diffusion processes, (2) intensive and rapid recharge after the glacial maximum down to several hundred meters depths, (3) a present-day regime of groundwater circulation limited to shallow depth. This work identifies important constraints regarding the mechanisms responsible for both marine and glacial fluid migrations and their preservation within a basement. It defines the first clear time scales of these processes and thus provides a unique case for understanding the effects of climate changes on hydrogeology in basements. It reveals that glacial water is supplied in significant amounts to deep aquifers even in permafrosted zones. It also emphasizes the vulnerability of modern groundwater hydrosystems to climate change as groundwater active aquifers is restricted to shallow depths.

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          Sulfur isotopic composition of cenozoic seawater sulfate

          A continuous seawater sulfate sulfur isotope curve for the Cenozoic with a resolution of approximately 1 million years was generated using marine barite. The sulfur isotopic composition decreased from 19 to 17 per mil between 65 and 55 million years ago, increased abruptly from 17 to 22 per mil between 55 and 45 million years ago, remained nearly constant from 35 to approximately 2 million years ago, and has decreased by 0.8 per mil during the past 2 million years. A comparison between seawater sulfate and marine carbonate carbon isotope records reveals no clear systematic coupling between the sulfur and carbon cycles over one to several millions of years, indicating that changes in the burial rate of pyrite sulfur and organic carbon did not singularly control the atmospheric oxygen content over short time intervals in the Cenozoic. This finding has implications for the modeling of controls on atmospheric oxygen concentration.
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            Nitrate dynamics in agricultural catchments deduced from groundwater dating and long-term nitrate monitoring in surface- and groundwaters.

            Although nitrate export in agricultural catchments has been simulated using various types of models, the role of groundwater in nitrate dynamics has rarely been fully taken into account. We used groundwater dating methods (CFC analyses) to reconstruct the original nitrate concentrations in the groundwater recharge in Brittany (Western France) from 1950 to 2009. This revealed a sharp increase in nitrate concentrations from 1977 to 1990 followed by a slight decrease. The recharge concentration curve was then compared with past chronicles of groundwater concentration. Groundwater can be interpreted as resulting from the annual dilution of recharge water in an uncontaminated aquifer. Two aquifers were considered: the weathered aquifer and the deeper fractured aquifer. The nitrate concentrations observed in the upper part of the weathered aquifer implied an annual renewal rate of 27 to 33% of the reservoir volume while those in the lower part indicated an annual renewal rate of 2-3%. The concentrations in the deep fractured aquifer showed an annual renewal rate of 0.1%. The river concentration can be simulated by combining these various groundwater reservoirs with the recharge. Winter and summer waters contain i) recharge water, or water from the variably saturated zone with rapid transfer and high nitrate concentrations, and ii) a large contribution (from 35 to 80% in winter and summer, respectively) from the lower part of the aquifer (lower weathered aquifer and deep fractured aquifer). This induces not only a relatively rapid response of the catchment to variations in agricultural pressure, but also a potential inertia which has to be taken into account.
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              Cooling of Tropical Brazil (5-Degrees-C) During the Last Glacial Maximum

              (1995)
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                Author and article information

                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group
                2045-2322
                22 September 2015
                2015
                : 5
                : 14132
                Affiliations
                [1 ]OSUR-Géosciences Rennes, Université Rennes 1 - CNRS , 35000 Rennes, France
                [2 ]BRGM, Laboratory Department, 3 av C. Guillemin , 45000 Orléans, France
                [3 ]OSUR-ECOBIO, Université Rennes 1 - CNRS , 35000 Rennes, France
                [4 ]Université de Nîmes, EA 7352 CHROME , 30021 Nîmes, France
                [5 ]CNRS/UPS UMR 8148 IDES, Université Paris-Sud, 91400 ORSAY France; P.A. GEOTOP, Université du Québec à Montréal , Montréal Qc, H3C 3P8, Canada
                [6 ]Aster Team Aix-Marseille Université, CNRS-IRD UM 34 CEREGE, Technopôle de l’Environnement Arbois-Méditerranée , 13545 Aix-en-Provence, France
                Author notes
                Article
                srep14132
                10.1038/srep14132
                4585752
                26392383
                8b51befc-c0cb-4a3b-9f6f-0fb6384b81e7
                Copyright © 2015, Macmillan Publishers Limited

                This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/

                History
                : 27 March 2015
                : 13 August 2015
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