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      Nanostructured Electrode Materials for Electrochemical Capacitor Applications

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          Abstract

          The advent of novel organic and inorganic nanomaterials in recent years, particularly nanostructured carbons, conducting polymers, and metal oxides, has enabled the fabrication of various energy devices with enhanced performance. In this paper, we review in detail different nanomaterials used in the fabrication of electrochemical capacitor electrodes and also give a brief overview of electric double-layer capacitors, pseudocapacitors, and hybrid capacitors. From a materials point of view, the latest trends in electrochemical capacitor research are also discussed through extensive analysis of the literature and by highlighting notable research examples (published mostly since 2013). Finally, a perspective on next-generation capacitor technology is also given, including the challenges that lie ahead.

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          Ionic liquids at electrified interfaces.

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            Polyaniline and polypyrrole pseudocapacitor electrodes with excellent cycling stability.

            Conducting polymers such as polyaniline and polypyrrole have been widely used as pseudocapacitive electrode materials for supercapacitors. However, their structural instability resulting from repeated volumetric swelling and shrinking during charge/discharge process has been a major hurdle for their practical applications. This work demonstrates a simple and general strategy to substantially enhance the cycling stability of conductive polymer electrodes by deposition of a thin carbonaceous shell onto their surface. Significantly, carbonaceous shell-coated polyaniline and polypyrrole electrodes achieved remarkable capacitance retentions of ∼95 and ∼85% after 10,000 cycles. Electron microscopy studies revealed that the presence of ∼5 nm thick carbonaceous shell can effective prevent the structural breakdown of polymer electrodes during charge/discharge process. Importantly, the polymer electrodes with a ∼5 nm thick carbonaceous shell exhibited comparable specific capacitance and pseudocapacitive behavior as the bare polymer electrodes. We anticipate that the same strategy can be applied for stabilizing other polymer electrode materials. The capability of fabricating stable polymer electrodes could open up new opportunities for pseudocapacitive devices.
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              Simultaneous formation of ultrahigh surface area and three-dimensional hierarchical porous graphene-like networks for fast and highly stable supercapacitors.

              A new one-step ion-exchange/activation combination method using a metal-ion exchanged resin as a carbon precursor is used to prepare a ultrahigh surface area and three-dimensional hierarchical porous graphene-like networks for fast and highly stable supercapacitors.
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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Nanomaterials (Basel)
                Nanomaterials (Basel)
                nanomaterials
                Nanomaterials
                MDPI
                2079-4991
                02 June 2015
                June 2015
                : 5
                : 2
                : 906-936
                Affiliations
                [1 ]Department of Polymer Engineering, Graduate School, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Korea; E-Mail: iyzvnzzang@ 123456gmail.com
                [2 ]School of Polymer Science and Engineering, Chonnam National University, 77 Yongbong-ro, Buk-gu, Gwangju 500-757, Korea
                Author notes
                [* ]Author to whom correspondence should be addressed; E-Mail: hyoon@ 123456chonnam.ac.kr ; Tel.: +82-62-530-1778; Fax: +82-62-530-1779.
                Article
                nanomaterials-05-00906
                10.3390/nano5020906
                5312909
                8d721513-f42f-4c1e-b0ef-fdd4ca39d12d
                © 2015 by the authors; licensee MDPI, Basel, Switzerland.

                This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 01 April 2015
                : 27 May 2015
                Categories
                Review

                nanomaterials,electrochemical capacitors,electric double-layer capacitors (edlcs),pseudocapacitors,hybrid capacitors

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