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      A flexible electromagnetic wave-electricity harvester

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          Abstract

          Developing an ultimate electromagnetic (EM)-absorbing material that can not only dissipate EM energy but also convert the generated heat into electricity is highly desired but remains a significant challenge. Here, we report a hybrid Sn@C composite with a biological cell-like splitting ability to address this challenge. The composite consisting of Sn nanoparticles embedded within porous carbon would split under a cycled annealing treatment, leading to more dispersed nanoparticles with an ultrasmall size. Benefiting from an electron-transmitting but a phonon-blocking structure created by the splitting behavior, an EM wave-electricity device constructed by the optimum Sn@C composite could achieve an efficiency of EM to heat at widely used frequency region and a maximum thermoelectric figure of merit of 0.62 at 473 K, as well as a constant output voltage and power under the condition of microwave radiation. This work provides a promising solution for solving EM interference with self-powered EM devices.

          Abstract

          Materials that can harvest electromagnetic (EM) waves and harness the resulting energy would have many applications. Here, the authors present a hybrid composite that produces thermoelectricity from the heating in the EM absorption under microwave radiation.

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          Most cited references39

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          Skin electronics from scalable fabrication of an intrinsically stretchable transistor array

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            Rationally Designing High-Performance Bulk Thermoelectric Materials.

            There has been a renaissance of interest in exploring highly efficient thermoelectric materials as a possible route to address the worldwide energy generation, utilization, and management. This review describes the recent advances in designing high-performance bulk thermoelectric materials. We begin with the fundamental stratagem of achieving the greatest thermoelectric figure of merit ZT of a given material by carrier concentration engineering, including Fermi level regulation and optimum carrier density stabilization. We proceed to discuss ways of maximizing ZT at a constant doping level, such as increase of band degeneracy (crystal structure symmetry, band convergence), enhancement of band effective mass (resonant levels, band flattening), improvement of carrier mobility (modulation doping, texturing), and decrease of lattice thermal conductivity (synergistic alloying, second-phase nanostructuring, mesostructuring, and all-length-scale hierarchical architectures). We then highlight the decoupling of the electron and phonon transport through coherent interface, matrix/precipitate electronic bands alignment, and compositionally alloyed nanostructures. Finally, recent discoveries of new compounds with intrinsically low thermal conductivity are summarized, where SnSe, BiCuSeO, MgAgSb, complex copper and bismuth chalcogenides, pnicogen-group chalcogenides with lone-pair electrons, and tetrahedrites are given particular emphasis. Future possible strategies for further enhancing ZT are considered at the end of this review.
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              Anomalous absorption of electromagnetic waves by 2D transition metal carbonitride Ti3CNT x (MXene).

              Lightweight, ultrathin, and flexible electromagnetic interference (EMI) shielding materials are needed to protect electronic circuits and portable telecommunication devices and to eliminate cross-talk between devices and device components. Here, we show that a two-dimensional (2D) transition metal carbonitride, Ti3CNT x MXene, with a moderate electrical conductivity, provides a higher shielding effectiveness compared with more conductive Ti3C2T x or metal foils of the same thickness. This exceptional shielding performance of Ti3CNT x was achieved by thermal annealing and is attributed to an anomalously high absorption of electromagnetic waves in its layered, metamaterial-like structure. These results provide guidance for designing advanced EMI shielding materials but also highlight the need for exploring fundamental mechanisms behind interaction of electromagnetic waves with 2D materials.
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                Author and article information

                Contributors
                rbwu@fudan.edu.cn
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                5 February 2021
                5 February 2021
                2021
                : 12
                : 834
                Affiliations
                [1 ]GRID grid.8547.e, ISNI 0000 0001 0125 2443, Department of Materials Science, , Fudan University, ; Shanghai, 200433 China
                [2 ]GRID grid.64938.30, ISNI 0000 0000 9558 9911, College of Materials Science and Technology, , Nanjing University of Aeronautics and Astronautics, ; Nanjing, 210016 China
                [3 ]GRID grid.67293.39, College of Mechanical and Vehicle Engineering, , Hunan University, ; Changsha, 410082 Hunan China
                [4 ]GRID grid.410645.2, ISNI 0000 0001 0455 0905, Institute of Materials for Energy and Environment, State Key Laboratory of Bio-fibers and Eco-textiles, College of Materials Science and Engineering, , Qingdao University, ; Qingdao, 266071 China
                [5 ]GRID grid.410625.4, ISNI 0000 0001 2293 4910, College of Materials Sciences and Engineering, , Nanjing Forestry University, ; Nanjing, 210037 China
                Author information
                http://orcid.org/0000-0001-7841-4594
                http://orcid.org/0000-0003-1761-8782
                http://orcid.org/0000-0002-3219-9996
                http://orcid.org/0000-0003-2815-2797
                Article
                21103
                10.1038/s41467-021-21103-9
                7864982
                33547310
                8dd007ad-5fe0-483f-a247-22707ef381c5
                © The Author(s) 2021

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 19 January 2020
                : 6 January 2021
                Funding
                Funded by: Recruitment Program of Global Youth Experts
                Categories
                Article
                Custom metadata
                © The Author(s) 2021

                Uncategorized
                devices for energy harvesting,electronic devices,nanoscale materials
                Uncategorized
                devices for energy harvesting, electronic devices, nanoscale materials

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