In the title compound, the acenapthylene ring system and the hydrazinecarbothioamide unit (=N—NH—C=S—NH–) are essentially coplanar, making a dihedral angle of 1.59 (9)°. The molecular conformation is stabilized by two weak intramolecular hydrogen bonds (N—H⋯O and N—H⋯N), which generate S(6) and S(5) ring motifs.
In the title compound, C 14H 11N 3OS, the acenaphthylene ring system and hydrazinecarbothioamide unit (=N—NH—C=S—NH–) are essentially coplanar [with maximum deviations from their mean planes of −0.009 (2) and 0.033 (2) Å, respectively], and make a dihedral angle of 1.59 (9)°. The molecular conformation is stabilized by two weak intramolecular hydrogen bonds (N—H⋯O and N—H⋯N), which generate S(6) and S(5) ring motifs. In the crystal, molecules are linked by N—H⋯S hydrogen bonds, forming chains along [010]. The chains are linked via pairs of C—H⋯O hydrogen bonds, enclosing R 2 2(10) ring motifs, and C—H⋯π interactions, forming a three-dimensional framework. The absolute structure of the title compound was determined by resonant scattering.