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      Green light activated hydrogen sensing of nanocrystalline composite ZnO-In 2O 3 films at room temperature

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          Abstract

          The possibility of reducing the operating temperature of H 2 gas sensor based on ZnO-In 2O 3 down to room temperature under green illumination is shown. It is found that sensitivity of ZnO-In 2O 3 composite to H 2 nonmonotonically depends on the oxides’ content. The optimal ratio between the components is chosen. The new mechanism of nanocrystalline ZnO-In 2O 3 sensor sensitivity to H 2 under illumination by green light is proposed. The mechanism considers the illumination turns the composite into nonequilibrium state and the photoconductivity change in the H 2 atmosphere is linked with alteration of nonequilibrium charge carriers recombination rate.

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          Most cited references33

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          Oxide Materials for Development of Integrated Gas Sensors—A Comprehensive Review

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            Zeolitic Imidazolate Framework Coated ZnO Nanorods as Molecular Sieving to Improve Selectivity of Formaldehyde Gas Sensor

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              Hydrogen-related defects in ZnO studied by infrared absorption spectroscopy

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                Author and article information

                Contributors
                as.ilin@physics.msu.ru
                Journal
                Sci Rep
                Sci Rep
                Scientific Reports
                Nature Publishing Group UK (London )
                2045-2322
                22 September 2017
                22 September 2017
                2017
                : 7
                : 12204
                Affiliations
                [1 ]ISNI 0000 0001 2342 9668, GRID grid.14476.30, Physics Department, Lomonosov Moscow State University, Leninskie Gory 1-2, ; Moscow, 119991 Russia
                [2 ]ISNI 0000 0004 0637 9621, GRID grid.424930.8, Semenov Institute of Chemical Physics, Russian Academia of Sciences, 4, Kosygina Str., ; Moscow, 119991 Russia
                [3 ]ISNI 0000000406204151, GRID grid.18919.38, National Research Centre “Kurchatov Institute”, 1, Akademika Kurchatova pl., ; Moscow, 123182 Russia
                [4 ]ISNI 0000000092721542, GRID grid.18763.3b, Moscow Institute of Physics and Technology (State University), 9, Institutskii per., Dolgoprudny, ; Moscow, Region 141700 Russia
                Article
                12547
                10.1038/s41598-017-12547-5
                5610332
                28939822
                920cd220-9f0e-4b2f-995e-2276af459db2
                © The Author(s) 2017

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 12 June 2017
                : 11 September 2017
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